Perspectives of in situ/operando resonant inelastic X-ray scattering in catalytic energy materials science

被引：34

作者：

Liu, Yi-Sheng ^{[1
]}

Glans, Per-Anders ^{[1
]}

Chuang, Cheng-Hao ^{[1
,2
]}

Kapilashrami, Mukes ^{[1
,3
]}

Guo, Jinghua ^{[1
,4
]}

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA

[2] Tamkang Univ, Dept Phys, Tamsui 250, Taiwan

[3] Univ Maryland, Dept Mech Engn, Ctr Engn Concepts Dev, College Pk, MD 20742 USA

[4] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 2015年 / 200卷

关键词：

Soft X-ray spectroscopy; Resonant soft X-ray emission spectroscopy; Resonant inelastic soft X-ray scattering; Energy materials; In situ/operando; ELECTRONIC-STRUCTURE; EMISSION-SPECTROSCOPY; FLUORESCENCE SPECTROSCOPY; CORE EXCITONS; ABSORPTION; COBALT; SPECTRA; WATER; EDGE; SIZE;

D O I：

10.1016/j.elspec.2015.07.004

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Growing environmental concerns have renewed the interest for light induced catalytic reactions to synthesize cleaner chemical fuels from syngas. This, however, requires a sound understanding for the dynamics taking place at molecular level as a result of light - matter interaction. We present herein the principles of soft X-ray resonant emission spectroscopy (RXES) and resonant inelastic scattering (RIXS) and the importance of these spectroscopic techniques in materials science in light of their unique ability to emanate characteristic fingerprints on the geometric structure, chemical bonding charge and spin states in addition to chemical sensitivity. The addition of in situ/operando RXES and RTXS capability offers new opportunities to project important material properties and functionalities under conditions nearly identical to the operational modes. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：282 / 292

页数：11

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