Calix[4]arene dimers; Self-assembly via hydrogen bonding at the upper rim

被引：35
|
作者：
Struck, O
Verboom, W
Smeets, WJJ
Spek, AL
Reinhoudt, DN
机构：
[1] UNIV TWENTE,LAB SUPRAMOL CHEM & TECHNOL,NL-7500 AE ENSCHEDE,NETHERLANDS
[2] UNIV UTRECHT,DEPT CRYSTAL & STRUCT CHEM,BIJVOET CTR BIOMOL RES,NL-3584 CH UTRECHT,NETHERLANDS
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1997年 / 02期
关键词：
D O I：
10.1039/a605586i
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The X-ray structure determination of calix[4]arenedicarboxylic acid unequivocally proves the self-assembled dimeric structure in the solid state, Also in apolar solvents two calix[4]arene molecules are connected via carboxylic acid moieties at the upper rim, NMR studies show that in polar solvents the calix[4]arenedicarboxylic acid is present as a monomer with a pinched cone conformation that differs from the dimeric structure in apolar solvents.
引用
收藏
页码：223 / 227
页数：5
相关论文
共 50 条
  • [1] Self-assembly of calix[4]arene amine derivatives
    O'Toole, Laura
    McGinley, John
    Creaven, Bernadette S.
    TETRAHEDRON, 2013, 69 (35) : 7220 - 7226
  • [2] Synthesis and self-assembly of chiral calix[4]arene aminols
    Zheng, YS
    Zhang, C
    ACTA CHIMICA SINICA, 2004, 62 (06) : 537 - 539
  • [3] Assembly of calix[4]arene carboxylic acid derivatives by hydrogen bonding
    Xiao, Zufeng
    Yang, Weiping
    Yan, Fengyi
    Ji, Lingbo
    Li, Wei
    Wang, Wei
    CRYSTENGCOMM, 2019, 21 (03) : 439 - 448
  • [4] Synthesis of upper rim calix[4]arene carcerands
    Kuhnert, Nikolai
    Le-Gresley, Adam
    TETRAHEDRON LETTERS, 2008, 49 (07) : 1274 - 1276
  • [5] Functionalisation of the upper rim of calix[4]arene via alcoholysis and hydrosilylation reactions
    Safa, Kazem D.
    Oskoei, Yones Mosaei
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (04) : 505 - 511
  • [6] Designing nanoporous crystalline materials by self-assembly:: 2D hydrogen-bonded networks from upper rim calix[4]arene diamide derivatives
    Baldini, Laura
    Sansone, Francesco
    Massera, Chiara
    Casnati, Alessandro
    Ugozzoli, Franco
    Ungaro, Rocco
    INORGANICA CHIMICA ACTA, 2007, 360 (03) : 970 - 980
  • [7] Enantioselective self-assembly of chiral calix[4]arene acid with amines
    Zheng, Yan-Song
    Ran, Shu-Yun
    Hu, Yu-Jian
    Liu, Xian-Xian
    CHEMICAL COMMUNICATIONS, 2009, (09) : 1121 - 1123
  • [8] FUNCTIONALIZATION OF CALIX[4]ARENE WITH HYDROXYALKYL GROUPS AT UPPER RIM
    HWANG, KL
    HAM, SH
    NO, KH
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1993, 14 (01) : 79 - 81
  • [9] SELF-ASSEMBLY VIA HYDROGEN BONDING AND METALLATION REACTIONS
    Raithby, Paul R.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1996, 52 : C265 - C265
  • [10] Sterically and guest-controlled self-assembly of calix[4]arene derivatives
    Shivanyuk, A
    Saadioui, M
    Broda, F
    Thondorf, I
    Vysotsky, MO
    Rissanen, K
    Kolehmainen, E
    Böhmer, V
    CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (09) : 2138 - 2148
12345