Novel environmentally friendly (Bi, Ca, Zn, La)VO4 inorganic yellow pigments

被引:31
|
作者
Wendusu [1 ]
Honda, Taihei [1 ]
Masui, Toshiyuki [1 ]
Imanaka, Nobuhito [1 ]
机构
[1] Osaka Univ, Dept Appl Chem, Fac Engn, Suita, Osaka 5650871, Japan
关键词
YTTRIUM CERATE SYNTHESIS; BIVO4; MOLYBDENUM;
D O I
10.1039/c3ra43978j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel inorganic yellow pigments, Bi1-x-y-zCaxZnyLazVO4-(x+ y)/2 (0.04 <= x <= 0.12; 0.01 <= y <= 0.05; 0.01 <= z <= 0.10) were synthesized as environmentally friendly inorganic materials, and their color properties were characterized. All the pigments exhibited brilliant yellow colors, and using the CIE L*a*b* system, the most vivid yellow hue was obtained for Bi0.85Ca0.08Zn0.02La0.05VO3.950 with a yellowness value (b*) of +93.5, which is much greater than that of a commercially available BiVO4 pigment (b*=+76.9). Since BiVO4 is an environmentally friendly inorganic yellow pigment, and Ca, Zn, and La are also nontoxic and safe elements, the Bi0.85Ca0.08Zn0.02La0.05VO3.950 pigment could be an effective alternative to conventional toxic yellow pigments.
引用
收藏
页码:24941 / 24945
页数:5
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