Novel polyoxometalate-phosphazene aggregates and their use as catalysts for biphasic oxidations with hydrogen peroxide

被引：42

作者：

Craven, Michael ^{[1
]}

Yahya, Rana ^{[1
]}

Kozhevnikova, Elena ^{[1
]}

Boomishankar, Ramamoorthy ^{[1
]}

Robertson, Craig M. ^{[1
]}

Steiner, Alexander ^{[1
]}

Kozhevnikov, Ivan ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

CHEMISTRY; DESULFURIZATION; EPOXIDATION; OLEFINS; OILS;

D O I：

10.1039/c2cc36793a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polyoxometalate-phosphazene salt aggregates comprising cyclophosphazene cations are highly efficient catalysts for environmentally benign biphasic oxidations with hydrogen peroxide. These catalysts self-assemble in situ simply by mixing commercial Keggin POMs and readily available phosphazenes.

引用

页码：349 / 351

页数：3

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