Process for preparing acid dyeable acrylonitrile copolymer in solution polymerization

被引:0
|
作者
Wang, YZ [1 ]
Gao, Y [1 ]
Jia, HG [1 ]
Gu, XH [1 ]
Shen, XY [1 ]
机构
[1] Qiqihar Univ, Coll Chem & Chem Engn, Qiqihar 161006, Peoples R China
来源
Proceedings of 2005 International Conference on Advanced Fibers and Polymer Materials (ICAFPM 2005), Vol 1 and 2: NEW CENTURY , NEW MATERIALS AND NEW LIFE | 2005年
关键词
acid dyeable; acrylonitrile; solution copolymerization;
D O I
暂无
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this paper an acid dyeable copolymer of acrylonitrile have been obtained by solution polymerization of acrylonitrile, alkaline monomer F. Taking AIBN as initiator the copolymer was carried Out in sodium sulfocyanate aqueous solution. The effect of initiator concentration on the polymer molecular weight and conversion of the polymerization were Studied. The relation between concentration of monomer F and the polymer conversion as well as concentration of monomer F and the ratio of dye-uptake of the copolymer were also investigated The influence of pH value was also talked about. At last, the structure of the copolymer was characterized by the IR and NMR. It can be shown that the copolymer has excellent acid dyeable characteristic.
引用
收藏
页码:1190 / 1193
页数:4
相关论文
共 35 条
  • [21] Preparation of Bismuth Tungstate/Preoxidized Acrylonitrile/Acrylic Acid Copolymer Composite Nanofiber Membrane and Its Photocatalytic Properties
    Fang, Yinchun
    Liu, Xinhua
    Li, Hongzhang
    Liu, Yanchun
    RECENT PATENTS ON NANOTECHNOLOGY, 2023, 17 (02) : 144 - 149
  • [22] Reverse atom-transfer radical polymerization of acrylonitrile catalyzed by FeCl3/iminodiacetic acid
    Hou, C
    Liu, JS
    Wang, CG
    POLYMER INTERNATIONAL, 2006, 55 (02) : 171 - 175
  • [23] FeCl3/Acetic Acid-mediated Reverse Atom Transfer Radical Polymerization of Acrylonitrile
    Ma, Jing
    Chen, Hou
    Zong, Guangxi
    Wang, Chunhua
    Liu, Delong
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2010, 47 (11): : 1075 - 1079
  • [24] Kinetic study of radical polymerization.: VII.: Investigation into the solution copolymerization of acrylonitrile and itaconic acid by real-time 1H NMR spectroscopy
    Mahdavian, Ali Reza
    Abdollahi, Mahdi
    JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 103 (05) : 3253 - 3260
  • [25] Direct pyrolysis mass spectrometry of acrylonitrile-cellulose graft copolymer prepared by radiation-induced graft polymerization in presence of styrene as homopolymer suppressor
    Badawy, SM
    Dessouki, AM
    El-Din, HMN
    RADIATION PHYSICS AND CHEMISTRY, 2001, 61 (02) : 143 - 148
  • [26] A novel poly[acrylonitrile-co-(3-ammoniumcarboxylate-butenoic acid-methylester)]copolymer for carbon fiber precursor
    Ju, An Qi
    Guang, Shan Yi
    Xu, Hong Yao
    CHINESE CHEMICAL LETTERS, 2012, 23 (11) : 1307 - 1310
  • [27] Solution Polymerization of Acrylic Acid Initiated by Redox Couple Na-PS/Na-MBS: Kinetic Model and Transition to Continuous Process
    Florit, Federico
    Rodrigues Bassam, Paola
    Cesana, Alberto
    Storti, Giuseppe
    PROCESSES, 2020, 8 (07)
  • [28] Pre-irradiation induced emulsion co-graft polymerization of acrylonitrile and acrylic acid onto a polyethylene nonwoven fabric
    Liu, Hanzhou
    Yu, Ming
    Ma, Hongjuan
    Wang, Ziqiang
    Li, Linfan
    Li, Jingye
    RADIATION PHYSICS AND CHEMISTRY, 2014, 94 : 129 - 132
  • [29] Preparation of Chelating Fabrics by Radiation-Induced Grafting of Itaconic Acid and Acrylonitrile onto Polypropylene Nonwoven Fabrics and Subsequent Amination of Graft Copolymer
    Zu, Jianhua
    Nho, Young Chang
    Jeun, Joon Pyo
    Liu, Ruiqin
    Liu, Li
    Yan, Feng
    Xia, Min
    JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 119 (06) : 3483 - 3489
  • [30] Synthesis and Characterization of Proton-conducting Polymer Electrolytes Based on Acrylonitrile-Styrene Sulfonic Acid Copolymer/Layered Double Hydroxides Nanocomposites
    Wang Angran
    Bao Yongzhong
    Weng Zhixue
    Huang Zhiming
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2008, 16 (06) : 938 - 943