The Adsorption Capacity of Metal-organic Framework Cu-BTC on N-hexane

被引：0

作者：

Li, Man-lin ^{[1
]}

Huang, Wei-qiu ^{[1
]}

Lv, Ai-hua ^{[1
]}

Huang, Zhou-lan ^{[2
]}

Huang, Shun-lin ^{[1
]}

机构：

[1] Changzhou Univ, Jiangsu Key Lab Oil & Gas Storage & Transportat T, Changzhou, Jiangsu, Peoples R China

[2] Univ Calgary, Dept Chem & Petr Engn, Calgary, AB, Canada

来源：

2018 3RD INTERNATIONAL CONFERENCE ON AUTOMATION, MECHANICAL AND ELECTRICAL ENGINEERING (AMEE 2018) | 2018年 / 298卷

基金：

中国国家自然科学基金;

关键词：

Cu-BTC; N-hexane; Flow rate; Temperature; Cyclic adsorption;

D O I：

暂无

中图分类号：

TP [自动化技术、计算机技术];

学科分类号：

0812 ;

摘要：

The objective of this work was to study the adsorption capacity of metal-organic framework Cu-BTC on n-hexane in terms of flow rate, temperature, and cyclic adsorption. The experiment was carried out under atmospheric pressure by a thermogravimeter analyzer. The experimental temperatures were 303K and 313K, and the n-hexane inlet flow rates were 50 and 100 mL min(-1). Four cycles of adsorption and desorption were performed. Thorough cleaning can increase the surface area of Cu-BTC. Adsorption equilibrium time decreases with increasing flow rate. The amount of adsorption is related to temperature and flow rates. The amount of adsorption decreases with increasing temperature and increasing flow. Absorption and desorption rate are almost constant after four cycles.

引用

页码：483 / 488

页数：6

共 4 条

[1] Comparison of adsorption isotherms on Cu-BTC metal organic frameworks synthesized from different routes
Chowdhury, Pradip
Bikkina, Chaitanya
Meister, Dirk
Dreisbach, Frieder
Gumma, Sasidhar
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 117 (1-2) : 406 - 413
[2] Critical Factors Driving the High Volumetric Uptake of Methane in Cu3(btc)2
Hulvey, Zeric
Vlaisavljevich, Bess
Mason, Jarad A.
Tsivion, Ehud
Dougherty, Timothy P.
Bloch, Eric D.
Head-Gordon, Martin
Smit, Berend
Long, Jeffrey R.
Brown, Craig M.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (33) : 10816 - 10825
[3] Comparison of the Behavior of Metal-Organic Frameworks and Zeolites for Hydrocarbon Separations
Peralta, David
Chaplais, Gerald
Simon-Masseron, Angelique
Barthelet, Karin
Chizallet, Celine
Quoineaud, Anne-Agathe
Pirngruber, Gerhard D.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (19) : 8115 - 8126
[4] Micro- and mesoporous CuBTCs for CO2/CH4 separation
Yoon, Hyung Chul
Rallapalli, Phani Brahma Somayajulu
Han, Sang Sup
Beum, Hee Tae
Jung, Tae Sung
Cho, Dong Woo
Ko, Minsu
Kim, Jong-Nam
[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2015, 32 (12) : 2501 - 2506

← 1 →