Metal-catalysed reactions of β-dicarbonyl compounds with fumaronitrile

被引：2
|
作者：
Veronese, AC
Callegari, R
Morelli, CF
Basato, M
机构：
[1] Univ Ferrara, Dipartimento Sci Farmaceut, I-44100 Ferrara, Italy
[2] Dipartimento Chim Inorgan Met Organ & Analit, Ctr Studio Stabil & Reattiv Composti Coordinaz, I-35131 Padua, Italy
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 142卷 / 03期
关键词：
fumaronitrile; beta-dicarbonyls; metal catalysis; carbon-carbon coupling;
D O I：
10.1016/S1381-1169(98)00328-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
beta-Dicarbonyl derivatives 1a-f react with fumaronitrile in the presence of catalytic amounts of [Ni(acac)(2)] or Ni(OAc)(2) to give 7-oxa-bicyclo[2,2,1]heptene derivatives 3a-f, while in similar experimental conditions, methyl malonate 1g affords the enaminodiester 5. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：373 / 376
页数：4
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