Surface-initiated reversible addition-fragmentation chain transfer polymerization from "clickable" polypropylene surface modified by iodine plasma activation

被引：7
|
作者：
Couturaud, B.
Mas, A.
Robin, Jean J. [1 ]
机构：
[1] CNRS, UMR 5253, Inst Charles Gerhardt, F-34095 Montpellier 5, France
来源：
EUROPEAN POLYMER JOURNAL | 2015年 / 70卷
关键词：
Surface; Iodine plasma; Activation; RAFT; Grafting; RADICAL POLYMERIZATION; SUBSTRATE; POLYETHYLENE; BRUSHES; DENSITY; HYBRIDS;
D O I：
10.1016/j.eurpolymj.2015.07.019
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
An iodine modified polypropylene surface was synthesized by iodine plasma activation. The obtained polypropylene surface was found to be a useful platform for secondary reactions. For instance, an azide-functionalized PP was prepared by nucleophilic exchange reaction. The surface was proven to be reactive toward R group of an alkyne modified RAFT agent via the copper-catalyzed azide-alkyne cycloaddition. RAFT mediated graft polymerization of methacrylic acid was carried out and lead to a controlled polymerization from the surface. Characterizations of the modified surface and the grafted polymers were performed through FTIR-GATR, XPS, AFM and colorimetric assays. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：276 / 285
页数：10
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