Iron Sulfide (FeS) Nanotubes Using Sulfurization of Hematite Nanowires

被引：76
作者：
Cummins, Dustin R. [1 ,2 ]
Russell, Harry B. [1 ,2 ]
Jasinski, Jacek B. [1 ,2 ]
Menon, Madhu [3 ]
Sunkara, Mahendra K. [1 ,2 ]
机构：
[1] Univ Louisville, Dept Chem Engn, Louisville, KY 40292 USA
[2] Univ Louisville, Conn Ctr Renewable Energy Res, Louisville, KY 40292 USA
[3] Univ Kentucky, Ctr Computat Sci, Lexington, KY 40506 USA
来源：
NANO LETTERS | 2013年 / 13卷 / 06期
基金：
美国国家科学基金会;
关键词：
FeS; troilite; nanotubes; Kirkendall effect; optical properties; sulfurization; hematite nanowire arrays; CHEMICAL-VAPOR-DEPOSITION; SELF-DIFFUSION; NICKEL-OXIDE; PYRITE; KIRKENDALL; FILMS; BATTERY; ARRAYS; LAYER;
D O I：
10.1021/nl400325s
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the phase transformation of hematite (alpha-Fe2O3) single crystal nanowires to crystalline FeS nanotubes using sulfurization with H2S gas at relatively low temperatures. Characterization indicates that phase pure hexagonal FeS nanotubes were formed. Time-series sulfurization experiments suggest epitaxial growth of FeS as a shell layer on hematite. This is the first report of hollow, crystalline FeS nanotubes with NiAs structure and also on the Kirkendall effect in solid-gas reactions with nanowires involving sulfurization.
引用
收藏
页码：2423 / 2430
页数：8
相关论文
共 42 条
  • [31] Electronic correlation effects in transition-metal sulfides
    Rohrbach, A
    Hafner, J
    Kresse, G
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (06) : 979 - 996
  • [32] ENERGY-BAND DIAGRAM FORPYRRHOTITE
    SAKKOPOULOS, S
    VITORATOS, E
    ARGYREAS, T
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1984, 45 (8-9) : 923 - 928
  • [33] PHOTOACTIVE THIN-FILM SEMICONDUCTING IRON PYRITE PREPARED BY SULFURIZATION OF IRON-OXIDES
    SMESTAD, G
    ENNAOUI, A
    FIECHTER, S
    TRIBUTSCH, H
    HOFMANN, WK
    BIRKHOLZ, M
    KAUTEK, W
    [J]. SOLAR ENERGY MATERIALS, 1990, 20 (03): : 149 - 165
  • [34] Soon J. M., 2007, APPL PHYS LETT, P91
  • [35] Inorganic nanowires: a perspective about their role in energy conversion and storage applications
    Sunkara, M. K.
    Pendyala, C.
    Cummins, D.
    Meduri, P.
    Jasinski, J.
    Kumar, V.
    Russell, H. B.
    Clark, E. L.
    Kim, J. H.
    [J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2011, 44 (17)
  • [36] Phase Transformation Studies of Metal Oxide Nanowires
    Thangala, Jyothish
    Chen, Zhiqiang
    Chin, Alan
    Ning, Cun-Zheng
    Sunkara, Mahendra K.
    [J]. CRYSTAL GROWTH & DESIGN, 2009, 9 (07) : 3177 - 3182
  • [37] PHOTO-ELECTROCHEMICAL ENERGY-CONVERSION INVOLVING TRANSITION-METAL D-STATES AND INTERCALATION OF LAYER COMPOUNDS
    TRIBUTSCH, H
    [J]. STRUCTURE AND BONDING, 1982, 49 : 127 - 175
  • [38] Surfactant-Assisted Hydrothermal Synthesis of Single phase Pyrite FeS2 Nanocrystals
    Wadia, Cyrus
    Wu, Yue
    Gul, Sheraz
    Volkman, Steven K.
    Guo, Jinghua
    Alivisatos, A. Paul
    [J]. CHEMISTRY OF MATERIALS, 2009, 21 (13) : 2568 - 2570
  • [39] Fabrication of the ordered FeS2 (pyrite) nanowire arrays in anodic aluminum oxide
    Wan, DY
    Wang, YT
    Zhou, ZP
    Yang, GQ
    Wang, BY
    Wei, L
    [J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2005, 122 (02): : 156 - 159
  • [40] Retention of biosignatures and mass-independent fractionations in pyrite: Self-diffusion of sulfur
    Watson, E. Bruce
    Cherniak, Daniele J.
    Frank, Elizabeth A.
    [J]. GEOCHIMICA ET COSMOCHIMICA ACTA, 2009, 73 (16) : 4792 - 4802
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