Oxygenation of saturated hydrocarbyl groups in the dinuclear Ni(III) bis(μ-oxo) complexes with the hydrotris(pyrazolyl)borate ligands TpR (R = Me3 and Pri2)

被引：0

作者：

Hikichi, S ^{[1
]}

Yoshizawa, M ^{[1
]}

Sasakura, Y ^{[1
]}

Komatsuzaki, H ^{[1
]}

Akita, M ^{[1
]}

Moro-oka, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 09期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intramolecular oxygenation of the Me and Pr-i substituents of Tp(R) to give the carboxylate (-CO2-) and enolate (-CMe=CHO-) groups, respectively, is mediated by the Ni(III)(2)-bis(mu-oxo) complexes in the presence of an excess amount of H2O2.

引用

页码：979 / 980

页数：2

共 22 条

[21] CHEMISTRY OF POLYNUCLEAR METAL-COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .59. REACTIONS OF THE ALKYLIDYNE COMPOUNDS [M(=CR)(CO)2(HB(PZ)3)][M=CR, MO, OR W, R=C6H4ME-4 - M=W, R=ME, HB(PZ)3=HYDROTRIS(PYRAZOL-1-YL)BORATE] WITH D10 COMPLEXES - CRYSTAL-STRUCTURE OF [PTW2(MU-CME)2(CO)4(HB(PZ)3)2]=
BECKE, SHF
BERMUDEZ, MD
TRANHUY, NH
HOWARD, JAK
JOHNSON, O
STONE, FGA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (05): : 1229 - 1234
[22] METAL-MEDIATED REDUCTION OF ALKANENITRILES TO IMIDO LIGANDS - FORMATION OF THE IMIDO COMPLEXES RE(NCH2R)X3(DPPBE) (R = ME, ET, I-PR, X = CL, BR) FROM THE REACTIONS OF THE OCTAHALODIRHENATE(III) ANIONS WITH 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE IN NITRILE SOLVENTS (RCN)
ESJORNSON, D
BAKIR, M
FANWICK, PE
JONES, KS
WALTON, RA
INORGANIC CHEMISTRY, 1990, 29 (11) : 2055 - 2061

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