Oxygenation of saturated hydrocarbyl groups in the dinuclear Ni(III) bis(μ-oxo) complexes with the hydrotris(pyrazolyl)borate ligands TpR (R = Me3 and Pri2)

被引：0

作者：

Hikichi, S ^{[1
]}

Yoshizawa, M ^{[1
]}

Sasakura, Y ^{[1
]}

Komatsuzaki, H ^{[1
]}

Akita, M ^{[1
]}

Moro-oka, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 09期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intramolecular oxygenation of the Me and Pr-i substituents of Tp(R) to give the carboxylate (-CO2-) and enolate (-CMe=CHO-) groups, respectively, is mediated by the Ni(III)(2)-bis(mu-oxo) complexes in the presence of an excess amount of H2O2.

引用

页码：979 / 980

页数：2

共 22 条

[1] First synthesis and structural characterization of dinuclear M(III) bis(μ-oxo) complexes of nickel and cobalt with hydrotris(pyrazolyl)borate ligand
Hikichi, S
Yoshizawa, M
Sasakura, Y
Akita, M
Moro-Oka, Y
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (40) : 10567 - 10568
[2] Variable Borohydride Hapticity in Nickel(II) Scorpionate Complexes [(TpR,Me)Ni(n-BH4)]: TpR,Me = hydrotris{3-R-5-methyl-1-pyrazolyl}borate; R = Ph, n=3 vs. R = Me, n=4
Kruse, Colin P.
Deb, Tapash
Aboelenen, Ahmed M.
Anderson, Caitlin M.
Petersen, Jeffrey L.
Jensen, Michael P.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (15-16) : 2474 - 2485
[3] Tetrahedral, highly coordinatively unsaturated 14e (Fe) and 15e (Co) hydrocarbyl complexes bearing hydrotris(pyrazolyl)borato ligands (TpR′), TpR′M-R (M = Fe, Co, Ni)
Shirasawa, N
Nguyet, TT
Hikichi, S
Moro-oka, Y
Akita, M
ORGANOMETALLICS, 2001, 20 (16) : 3582 - 3598
[4] SYNTHESIS AND STRUCTURE OF BIS[HYDROTRIS(3,5-DIMETHYLPYRAZOLYL)BORATO]IODOURANIUM(III), U[HB(3,5-ME(2)PZ)(3)]I-2 - UNPRECEDENTED SIDE-ON INTERACTION INVOLVING A HYDROTRIS(PYRAZOLYL)BORATE LIGAND
SUN, YM
MCDONALD, R
TAKATS, J
DAY, VW
EBERSPACHER, TA
INORGANIC CHEMISTRY, 1994, 33 (20) : 4433 - 4434
[5] HYDROTRIS(PYRAZOLYL)BORATE CHEMISTRY OF URANIUM(III) AND URANIUM(IV) - SYNTHESIS OF DELTA-HYDROCARBYL DERIVATIVES OF URANIUM(IV) AND REACTIVITY OF UCL2R[HB(3,5-ME2PZ)3] (R = CH2SIME3, CH(SIME3)2) AND UCL2[HB(3,5-ME2PZ)3] TOWARD KETONES AND ALDEHYDES
DOMINGOS, A
MARQUES, N
DEMATOS, AP
SANTOS, I
SILVA, M
ORGANOMETALLICS, 1994, 13 (02) : 654 - 662
[6] Novel (methyl)- and (acetyl)palladium complexes containing bis(pyrazolyl)borate ligands -: Dynamic equilibrium between η2 and η1 forms for the complex Bp*(Me)(PCy3)Pd [Bp* = dihydridobis(3,5-dimethylpyrazolyl)borate]
Díaz-Requejo, MM
Nicasio, MC
Belderrain, TR
Pérez, PJ
Puerta, MC
Valerga, P
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2000, (06) : 1359 - 1364
[7] Structural characterization and intramolecular aliphatic C-H oxidation ability of MIII (μ-O)2MIII complexes of Ni and Co with the hydrotris-(3,5-dialkyl-4-X-pyrazolyl)borate ligands TpMe2,X (X = Me, H, Br) and TpiPr2
Hikichi, S
Yoshizawa, M
Sasakura, Y
Komatsuzaki, H
Moro-oka, Y
Akita, M
CHEMISTRY-A EUROPEAN JOURNAL, 2001, 7 (23) : 5011 - +
[8] SYNTHESIS AND STRUCTURE OF THE FIRST BIS-HYDROTRIS(3-(T)BU-5-ME PYRAZOLYL)BORATE COMPLEXES, LN(TP(T)BU,ME)(2) (LN=SM, YB) - FLUXIONALITY, BONDING MODE EXCHANGE AND B-H-LN BRIDGE BONDING
ZHANG, XW
MCDONALD, R
TAKATS, J
NEW JOURNAL OF CHEMISTRY, 1995, 19 (5-6) : 573 - 585
[9] N/O- and C-bound (enolato)palladium complexes with hydrotris(pyrazolyl)borato ligands (TpR: R = iPr2, Me2) obtained via dehydrative condensation between the hydroxo complexes TpRPd(Py)OH and active methylene compounds:: Factors determining the isomer distribution and dimerization of cyano compounds
Kujime, M
Hikichi, S
Akita, M
ORGANOMETALLICS, 2001, 20 (19) : 4049 - 4060
[10] Reactivity of molybdenum complexes containing both NHNPhR and NNPhR ligands (R = Ph, Me) toward hydridotris(pyrazolyl)borate, Tp and hydridotris(3,5-dimethylpyrazolyl)borate Tp*, ligands.: X-ray crystal structure of [TpMo(NNMePh)2Cl]
Manzur, C
Carrillo, D
Robert, F
Gouzerh, P
Hamon, P
Hamon, JR
INORGANICA CHIMICA ACTA, 1998, 268 (02) : 199 - 204

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