Determination of Au, Pt, Pd in gold ore mineral raw materials by stripping voltammetry

被引:0
作者
Kolpakova, N. A. [1 ]
Oskina, Y. A. [1 ]
Panova, S. M. [1 ]
Pshenichkin, A. Ya. [1 ]
机构
[1] Tomsk Polytech Univ, Tomsk 634050, Russia
来源
CHEMISTRY AND CHEMICAL TECHNOLOGY IN XXI CENTURY (CCT 2016) | 2016年 / 85卷
关键词
METALS;
D O I
10.1051/matecconf/20168501012
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The paper considers the possibilities of use of the method of stripping voltammetry for finding platinum metals in mineral gold and ore raw material. A review of new options of electro-concentration of platinum metals on the surface of graphite electrode with the following sediment electro-oxidation and receipt of an analytical signal is presented: platinum finding was carried out by picks of selective electrooxidation of iridium from intermetallic compound with platinum; gold finding was carried out by picks of gold electro-oxidation on the surface of graphite electrode modified by bismuth; palladium finding was performed by picks of palladium electro-oxidation on the surface of graphite electrode. 1M HCL solution was selected as a supporting electrolyte. Gold and hydrogen elimination on the process of palladium electro-oxidation was performed by means of UV irradiation of solution in the process of electroconcentration of palladium sediment. Gold, platinum and palladium determination was carried out in mineral gold and ore raw material of Verkhneamylskiy gold and ore district.
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页数:3
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