Tris(2-pyridyl)phosphine oxide:: how C-H•••O and C-H•••N interactions can affect crystal packing efficiency

被引:11
作者
Bowen, RJ [1 ]
Fernandes, MA [1 ]
Gitari, PW [1 ]
Layh, M [1 ]
机构
[1] Univ Witwatersrand, Sch Chem, Inst Mol Sci, ZA-2050 Wits, South Africa
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷
关键词
D O I
10.1107/S0108270104003956
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tris( 2-pyridyl) phosphine oxide, (I), C15H12N3OP, is isomorphous with tris(2-pyridyl) phosphine. Because of a combination of C-H...O and C-H...N interactions, the crystal packing is denser in the title compound than in the related compounds triphenylphosphine oxide and tris(2-pyridyl)phosphine.
引用
收藏
页码:O258 / O260
页数:3
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