Synthesis, Structure and Gas-Phase Reactivity of a Silver Hydride Complex [Ag3{(PPh2)2CH2}3(μ3-H)(μ3-Cl)]BF4

被引：42

作者：

Zavras, Athanasios ^{[1
,2
]}

Khairallah, George N. ^{[1
,2
]}

Connell, Timothy U. ^{[1
,2
]}

White, Jonathan M. ^{[1
,2
]}

Edwards, Alison J. ^{[3
]}

Donnelly, Paul S. ^{[1
,2
]}

O'Hair, Richard A. J. ^{[1
,2
]}

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia

[2] Univ Melbourne, Mol Sci & Biotechnol Inst Bio21, Parkville, Vic 3010, Australia

[3] Australian Nucl Sci & Technol Org, Bragg Inst, Lucas Heights, NSW 2234, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 32期

基金：

澳大利亚研究理事会;

关键词：

cluster compounds; gas-phase reactions; mass spectrometry; silver hydride; X-ray crystallography; RAY CRYSTAL-STRUCTURE; CLUSTER CATIONS; C-I; CORE; BR; ACTIVATION; HYDROGEN; ALUMINA; C-60; FORM;

D O I：

10.1002/anie.201302436

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mass spectrometry shows the way! MS analysis of silver salts treated with sodium borohydride in the presence of a bis(phosphino) ligand revealed the formation of novel silver hydride nanocluster cations instead of all silver nanocluster cations. This serendipitous discovery prompted the condensed-phase synthesis, isolation, and characterization of [Ag3{(Ph 2P)2CH2}3(μ3-H) (μ3-Cl)]BF4×0.5 CHCl3. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8391 / 8394

页数：4

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