Synthesis of graphene-wrapped CuO hybrid materials by CO2 mineralization

被引:52
作者
Ko, Jong Wan [1 ]
Kim, Sung-Wook [2 ]
Hong, Jihyun [2 ]
Ryu, Jungki [1 ]
Kang, Kisuk [2 ]
Park, Chan Beum [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
[2] Seoul Natl Univ, Dept Mat Sci & Engn, Seoul 151742, South Korea
基金
新加坡国家研究基金会;
关键词
LITHIUM ION BATTERIES; CALCIUM-CARBONATE; ANODE MATERIALS; THIN-FILMS; OXIDE; PERFORMANCE; CACO3; NANOCOMPOSITE; COMPOSITES; STORAGE;
D O I
10.1039/c2gc35560d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene-wrapped metal oxide hybrid materials are synthesized through inspiration from natural CO2 mineralization. We created hierarchical, nanostructured graphene/metal oxide by converting a CO2-mineralized graphene oxide/CaCO3 precursor to metal-based minerals such as graphene- wrapped CuO hybrid materials, which highly enhanced the stability and recyclability of the CuO anode for Li ion batteries. The synthesis of graphene-wrapped metal oxide and its application to Li ion battery electrodes suggest a new possibility for hybridizing graphene and metal oxide nanoparticles using the inspiration of natural mineralization.
引用
收藏
页码:2391 / 2394
页数:4
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