Rapid hydrolysis of 2′,3′-cAMP with a Cu(II) complex:: Effect of intramolecular hydrogen bonding on the basicity and reactivity of a metal-bound hydroxide

被引：103

作者：

Wall, M ^{[1
]}

Linkletter, B ^{[1
]}

Williams, D ^{[1
]}

Lebuis, AM ^{[1
]}

Hynes, RC ^{[1
]}

Chin, J ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1999年 / 121卷 / 19期

关键词：

D O I：

10.1021/ja981227l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：4710 / 4711

页数：2

共 19 条

[1] CATALYTIC HYDROLYSIS OF 2',3'-CYCLIC ADENOSINE-MONOPHOSPHATE BY AQUA(2,2' - 6',2''-TERPYRIDINE)COPPER(II) - BREAKDOWN OF THE ANALOGY BETWEEN ACTIVATED PHOSPHODIESTERS AND RNA [J].

BASHKIN, JK ;

JENKINS, LA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (23) :3631-3632

[2] EFFECTS OF METAL-IONS, INCLUDING MG2+ AND LANTHANIDES, ON THE CLEAVAGE OF RIBONUCLEOTIDES AND RNA MODEL COMPOUNDS [J].

BRESLOW, R ;

HUANG, DL .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1991, 88 (10) :4080-4083

[3] SELECTIVE CATALYTIC HYDROLYSIS OF A SIMPLE PHOSPHODIESTER BY A MACROCYCLIC COPPER(II) COMPLEX [J].

BURSTYN, JN ;

DEAL, KA .

INORGANIC CHEMISTRY, 1993, 32 (17) :3585-3586

[4] DIRECT MEASUREMENT OF TRANSITION-STATE BOND-CLEAVAGE IN HYDROLYSIS OF PHOSPHATE-ESTERS OF P-NITROPHENOL [J].

HENGGE, AC ;

CLELAND, WW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (20) :7421-7422

[5]

JENCKS WP, 1970, HDB BIOCHEMISTRY, pJ150

[6] NONLINEAR STRUCTURE-REACTIVITY CORRELATIONS . IMIDAZOLE-CATALYZED HYDROLYSIS OF ESTERS [J].

KIRSCH, JF ;

JENCKS, WP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (05) :837-&

[7] Rapid phosphodiester hydrolysis by an ammonium-functionalized copper(II) complex. A model for the cooperativity of metal ions and NH-acidic groups in phosphoryl transfer enzymes [J].

Kovari, E ;

Kramer, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (50) :12704-12709

[8] RAPID HYDROLYSIS OF RNA WITH A CU-II COMPLEX [J].

LINKLETTER, B ;

CHIN, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (04) :472-474

[9]

LINKLETTER B, 1995, THESIS MCGILL U CANA

[10] Catalysis of phosphodiester transesterification by Cu(II)-terpyridine complexes with peripheral pendent base groups: Implications for the mechanism [J].

Liu, SH ;

Hamilton, AD .

TETRAHEDRON LETTERS, 1997, 38 (07) :1107-1110

← 1 2 →