A new radical synthesis of allenes

被引：39

作者：

Delouvrié, B ^{[1
]}

Lacôte, E ^{[1
]}

Fensterbank, L ^{[1
]}

Malacria, M ^{[1
]}

机构：

[1] Univ Paris 06, Lab Chim Organ Synth, CNRS, F-75252 Paris, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(99)00547-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The unprecedented radical beta-elimination of vinylsulfoxides opens a new access to functionalized di- and trisubstituted allenes. The radical precursors are obtained in two steps from a carbonyl derivative and a vinylsulfoxide. The radical translocation trick can also be used to trigger the beta-elimination of the sulfinyl radical. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：3565 / 3568

页数：4

共 23 条

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