Copper (I) and (II) complexes of melamine

被引：54
|
作者：
Wiles, AB
Bozzuto, D
Cahill, CL
Pike, RD
机构：
[1] Coll William & Mary, Dept Chem, Williamsburg, VA 23187 USA
[2] George Washington Univ, Dept Chem, Washington, DC 20052 USA
来源：
POLYHEDRON | 2006年 / 25卷 / 03期
基金：
美国国家科学基金会;
关键词：
copper; complex; infrared; melamine; thermogravimetry; X-ray;
D O I：
10.1016/j.poly.2005.08.022
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Coordination of copper (1) and (11) salts to melamine (Mel) produces [CuX(Mel)] [X = Cl (5a), Br (5b), I (5c), NO3 (5d)], [CuX2-(Mel)(2)] center dot S [X = Cl, S = H2O (6a); X = Cl, S = 2 MeOH (6b); X = Br, S = 1/2H(2)O (6c); X = OAc, S = none (6d)], and [Cu(OAC)(2)(Mel)] (7). The chemical identity of the complexes has been confirmed by elemental analysis, X-ray powder diffraction, thermogravimetry, and infrared analysis. (c) 2005 Elsevier Ltd. All rights reserved.
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页码：776 / 782
页数：7
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