A microporous metal-organic framework for gas-chromatographic separation of alkanes

被引：1170
作者：
Chen, BL [1 ]
Liang, CD
Yang, J
Contreras, DS
Clancy, YL
Lobkovsky, EB
Yaghi, OM
Dai, S
机构：
[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78541 USA
[2] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
[3] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA
[4] Cornell Univ, Baker Lab, Dept Chem & Biol Chem, Ithaca, NY 14853 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 09期
关键词：
alkanes; gas chromatography; metal-organic frameworks; microporous materials; sorption;
D O I：
10.1002/anie.200502844
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Filling the pores: A zinc-based metal-organic framework (MOF) can be transformed reversibly from an open (a) to a dense (b) configuration. The microporous solid is the first example of a MOF that is highly selective in the gas-chromatographic separation of alkanes. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：1390 / 1393
页数：4
相关论文
共 50 条
[31]   A robust porous material constructed of linear coordination polymer chains: Reversible single-crystal to single-crystal transformations upon dehydration and rehydration [J].
Lee, EY ;
Suh, MP .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (21) :2798-2801
[32]   Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions [J].
Ma, BQ ;
Mulfort, KL ;
Hupp, JT .
INORGANIC CHEMISTRY, 2005, 44 (14) :4912-4914
[33]   Expanding and shrinking porous modulation based on pillared-layer coordination polymers showing selective guest adsorption [J].
Maji, TK ;
Uemura, K ;
Chang, HC ;
Matsuda, R ;
Kitagawa, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (25) :3269-3272
[34]  
Maji TK, 2004, ANGEW CHEM, V116, P3331
[35]   Tracer chromatographic study of pore and pore mouth adsorption of linear and monobranched alkanes on ZSM-22 zeolite [J].
Ocakoglu, RA ;
Denayer, JFM ;
Marin, GB ;
Martens, JA ;
Baron, GV .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (01) :398-406
[36]   Microporous metal organic materials: Promising candidates as sorbents for hydrogen storage [J].
Pan, L ;
Sander, MB ;
Huang, XY ;
Li, J ;
Smith, M ;
Bittner, E ;
Bockrath, B ;
Johnson, JK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (05) :1308-1309
[37]   RPM-1: A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption [J].
Pan, L ;
Liu, HM ;
Lei, XG ;
Huang, XY ;
Olson, DH ;
Turro, NJ ;
Li, J .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (05) :542-+
[38]  
PAN L, 2003, ANGEW CHEM, V115, P560
[39]  
Rao C. N. R., 2004, ANGEW CHEM, V116, P1490
[40]   Metal carboxylates with open architectures [J].
Rao, CNR ;
Natarajan, S ;
Vaidhyanathan, R .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (12) :1466-1496
12345