A microporous metal-organic framework for gas-chromatographic separation of alkanes

被引:1155
作者
Chen, BL [1 ]
Liang, CD
Yang, J
Contreras, DS
Clancy, YL
Lobkovsky, EB
Yaghi, OM
Dai, S
机构
[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78541 USA
[2] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
[3] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA
[4] Cornell Univ, Baker Lab, Dept Chem & Biol Chem, Ithaca, NY 14853 USA
关键词
alkanes; gas chromatography; metal-organic frameworks; microporous materials; sorption;
D O I
10.1002/anie.200502844
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Filling the pores: A zinc-based metal-organic framework (MOF) can be transformed reversibly from an open (a) to a dense (b) configuration. The microporous solid is the first example of a MOF that is highly selective in the gas-chromatographic separation of alkanes. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1390 / 1393
页数:4
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