The absolute stereochemistry of the ester functions of fumouisin B1

被引：11

作者：

Edwards, OE

Blackwell, BA ^{[1
]}

Driega, AB

Bensimon, C

ApSimon, JW

机构：

[1] Carleton Univ, Ottawa Carleton Chem Inst, Ottawa, ON K1S 5B6, Canada

[2] Agr & Agri Food Canada, Eastern Cereal & Oilseed Res Ctr, Ottawa, ON K1A 0C6, Canada

[3] MDS Nordion, Kanata, ON K2K 1X8, Canada

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 24期

关键词：

fumonisins; TCA ester configuration; R(-) 3-(2 '-hydroxylethyl)-(gamma)-butyrolactone;

D O I：

10.1016/S0040-4039(99)00824-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis of an optically active gamma-lactone related to tricarballylic acid (TCA) and correlation of this to the same lactone derived from the two sidechain TCA esters at C-14 and C-15 of fumonisin B(1) has established that these esters have the R configuration. Crown copyright (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：4515 / 4518

页数：4

共 18 条

[1]

APSIMON JW, 1994, TETRAHEDRON LETT, V35, P7703, DOI 10.1016/0040-4039(94)80097-9

[2] STRUCTURE ELUCIDATION OF THE FUMONISINS, MYCOTOXINS FROM FUSARIUM-MONILIFORME [J].