Autothermal reforming of gasoline using a cool flame vaporizer

被引:13
作者
da Silva, JM
Hermann, I
Mengel, C [1 ]
Lucka, K
Köhne, H
机构
[1] Rhein Westfal TH Aachen, Dept Heat & Mass Transfer, D-52056 Aachen, Germany
[2] Adam Opel AG, Global Alternat Prop Ctr, D-65423 Russelsheim, Germany
关键词
autothermal reforming; cool flames; premixing; fuel cell;
D O I
10.1002/aic.10100
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The phenomenon of cool flames can be used for mixing, evaporation, and overheating of a mixture of fuel, air, and steam. This method is used to provide a homogeneous mixture preparation. This study investigates the existence of cool flames running a stationary cool flame reactor under autothermal reforming conditions. It particularly characterizes the thermal limits of the cool flame reaction at high steam-to-carbon ratios. The experiments show that a cool flame vaporizer can be combined with an autothermal reformer leading to a homogeneous temperature profile in the front of the catalyst bed. This results in a good conversion of the fuel in the reforming process. (C) 2004 American Institute of Chemical Engineers AIChE J, 50: 1042-1050, 2004
引用
收藏
页码:1042 / 1050
页数:9
相关论文
共 19 条
[1]  
[Anonymous], 1997, Low-Temperature Combustion and Autoignition
[2]   A comprehensive modeling study of iso-octane oxidation [J].
Curran, HJ ;
Gaffuri, P ;
Pitz, WJ ;
Westbrook, CK .
COMBUSTION AND FLAME, 2002, 129 (03) :253-280
[3]   A comprehensive modeling study of n-heptane oxidation [J].
Curran, HJ ;
Gaffuri, P ;
Pitz, WJ ;
Westbrook, CK .
COMBUSTION AND FLAME, 1998, 114 (1-2) :149-177
[4]   EXPERIMENTAL-STUDY OF THE OXIDATION OF N-HEPTANE IN A JET-STIRRED REACTOR FROM LOW-TEMPERATURE TO HIGH-TEMPERATURE AND PRESSURES UP TO 40-ATM [J].
DAGAUT, P ;
REUILLON, M ;
CATHONNET, M .
COMBUSTION AND FLAME, 1995, 101 (1-2) :132-140
[5]   HIGH-PRESSURE OXIDATION OF LIQUID FUELS FROM LOW TO HIGH-TEMPERATURE .1. N-HEPTANE AND ISOOCTANE [J].
DAGAUT, P ;
REUILLON, M ;
CATHONNET, M .
COMBUSTION SCIENCE AND TECHNOLOGY, 1994, 95 (1-6) :233-260
[6]   Comprehensive kinetic model for the low-temperature oxidation of hydrocarbons [J].
Gaffuri, P ;
Faravelli, T ;
Ranzi, E ;
Cernansky, NP ;
Miller, D ;
dAnna, A ;
Ciajolo, A .
AICHE JOURNAL, 1997, 43 (05) :1278-1286
[7]  
HARTMANN L, 2000, P HYFO RUM 2000, V2
[8]  
HERMAN I, 2001, ENTWICKLUNG VERDAMPF, P25
[9]   The production of benzene in the low-temperature oxidation of cyclohexane, cyclohexene, and cyclohexa-1,3-diene [J].
Lemaire, O ;
Ribaucour, M ;
Carlier, M ;
Minetti, R .
COMBUSTION AND FLAME, 2001, 127 (1-2) :1971-1980
[10]  
LIGNOLA PG, 1988, 22 S INT COMB COMB I, P1625