Cationic Organophosphorus Chromophores: A Diamond in the Rough among Ionic Dyes

被引：28

作者：

Belyaev, Andrey ^{[1
]}

Chou, Pi-Tai ^{[2
]}

Koshevoy, Igor O. ^{[1
]}

机构：

[1] Univ Eastern Finland, Dept Chem, Joensuu 80101, Finland

[2] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2021年 / 27卷 / 02期

基金：

芬兰科学院;

关键词：

anion– cation interactions; ionic dyes; organophosphorus chromophores; phosphonium salts; phosphorus heterocycles; AGGREGATION-INDUCED EMISSION; PHOSPHONIUM SALTS; PHOTOPHYSICAL PROPERTIES; REDUCTIVE ELIMINATION; CATALYZED SYNTHESIS; OPTICAL-PROPERTIES; ELECTRON-ACCEPTOR; ARYL-PHOSPHONIUM; CHARGE-TRANSFER; FLUORESCENCE;

D O I：

10.1002/chem.202001853

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tunable electron-accepting properties of the cationic phosphorus center, its geometry and unique preparative chemistry that allows combining this unit with diversity of pi-conjugated motifs, define the appealing photophysical and electrochemical characteristics of organophosphorus ionic chromophores. This Minireview summarizes the achievements in the synthesis of the pi-extended molecules functionalized with P-cationic fragments, modulation of their properties by means of structural modification, and emphasizes the important effect of cation-anion interactions, which can drastically change physical behavior of these two-component systems.

引用

页码：537 / 552

页数：16

共 142 条

[1] Ionic aggregation-induced emission dye with bulky counterions for preparation of bright near-infrared polymeric nanoparticles [J].

Adarsh, Nagappanpillai ;

Klymchenko, Andrey S. .

NANOSCALE, 2019, 11 (29) :13977-13987

[2] EPR and DFT studies of the one-electron reduction product of phospholium cations [J].

Adkine, P ;

Cantat, T ;

Deschamps, E ;

Ricard, L ;

Mézailles, N ;

Le Floch, P ;

Geoffroy, M .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (07) :862-868

[3] Tuning of the optical properties and Lewis acidity of dibenzopnictogenaborins by modification on bridging main group elements [J].

Agou, Tomohiro ;

Kobayashi, Junji ;

Kawashima, Takayuki .

INORGANIC CHEMISTRY, 2006, 45 (22) :9137-9144

[4] Two-photon absorption properties of heterafluorenes and spirobiheterafluorenes bearing aminostyryl arms [J].

Agou, Tomohiro ;

Hossain, Md. Delwar ;

Kawashima, Takayuki ;

Kamada, Kenji ;

Ohta, Koji .

CHEMICAL COMMUNICATIONS, 2009, (44) :6762-6764

[5] Electrofluorochromic systems: Molecules and materials exhibiting redox-switchable fluorescence [J].

Al-Kutubi, Hanan ;

Zafarani, Hamid Reza ;

Rassaei, Liza ;

Mathwig, Klaus .

EUROPEAN POLYMER JOURNAL, 2016, 83 :478-498

[6] Insertion of Benzynes into the P=N Bond of P-Alkenyl(alkynyl)-λ5-phosphazenes [J].

Alajarin, Mateo ;

Lopez-Leonardo, Carmen ;

Raja, Rosalia ;

Orenes, Raul-Angel .

ORGANIC LETTERS, 2011, 13 (20) :5668-5671

[7] Anticancer Agents: Does a Phosphonium Behave Like a Gold(I) Phosphine Complex? Let a "Smart" Probe Answer! [J].

Ali, Moussa ;

Dondaine, Lucile ;

Adolle, Anais ;

Sampaio, Carla ;

Chotard, Florian ;

Richard, Philippe ;

Denat, Franck ;

Bettaieb, Ali ;

Le Gendre, Pierre ;

Laurens, Veronique ;

Goze, Christine ;

Paul, Catherine ;

Bodio, Ewen .

JOURNAL OF MEDICINAL CHEMISTRY, 2015, 58 (11) :4521-4528

[8] Synthesis, spectroscopic studies and structural characterisation of some new 2-(phosphonioaryl)imidazolide betaines [J].

Allen, DW ;

Hawkrigg, J ;

Adams, H ;

Taylor, BF ;

Hibbs, DE ;

Hursthouse, MB .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (02) :335-340

[9] Synthesis and solvatochromism of some dipolar aryl-phosphonium and -phosphine oxide systems [J].

Allen, DW ;

Mifflin, JP ;

Skabara, PJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 601 (02) :293-298

[10] Solvatochromic and halochromic properties of some phosphonioarylimino- and phosphonioarylazo-phenolate betaine dyes [J].

Allen, DW ;

Li, X .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1997, (06) :1099-1103

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