Production of 1,5-pentanediol from biomass via furfural and tetrahydrofurfuryl alcohol

被引：136
作者：
Nakagawa, Yoshinao [1 ]
Tomishige, Keiichi [1 ]
机构：
[1] Tohoku Univ, Sch Engn, Dept Appl Chem, Aoba Ku, Sendai, Miyagi 9808579, Japan
来源：
CATALYSIS TODAY | 2012年 / 195卷 / 01期
关键词：
Hydrogenolysis; Biomass; Tetrahydrofurfuryl alcohol; Rhodium; Heterogeneous catalysis; ION-EXCHANGE-RESIN; GLYCEROL HYDROGENOLYSIS; CATALYST; HYDROGENATION; 1,2-PROPANEDIOL; ETHERS; FUELS; 1,3-PROPANEDIOL; DEOXYGENATION; CONVERSION;
D O I：
10.1016/j.cattod.2012.04.048
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Production of 1,5-pentanediol from tetrahydrofurfuryl alcohol, which can be produced from biomass via furfural, is reviewed. Silica-or carbon-supported rhodium catalysts modified with Re, Mo or W show high activity and selectivity, while commercial hydrogenation catalysts such as Ru/C, copper chromite and Raney Ni show much lower activity and selectivity. The formation of metal bond between rhodium metal particles and additive metal is a key to the high performance. The reaction mechanism is discussed based on the characterization data, reactivity of related substrates and kinetics. (C) 2012 Elsevier B.V. All rights reserved.
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收藏
页码：136 / 143
页数：8
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