Collapsed Cu(II)-Hydroxamate Metallacrowns

被引：25

作者：

Golenya, Irina A. ^{[2
]}

Gumienna-Kontecka, Elzbieta ^{[1
]}

Boyko, Alexander N. ^{[2
]}

Haukka, Matti ^{[3
]}

Fritsky, Igor O. ^{[2
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

[2] Natl Taras Shevchenko Univ, Dept Chem, UA-01601 Kiev, Ukraine

[3] Univ Joensuu, Dept Chem, FI-80101 Joensuu, Finland

来源：

INORGANIC CHEMISTRY | 2012年 / 51卷 / 11期

关键词：

COPPER(II) COMPLEXES; AMINOHYDROXAMIC ACIDS; AQUEOUS-SOLUTION; 12-METALLACROWN-4; COMPLEXES; METAL-COMPLEXES; OXIME LIGANDS; X-RAY; DERIVATIVES; CONVERSION; AGENTS;

D O I：

10.1021/ic300387e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Degradation of a strained, thermodynamically destabilized pentanuclear copper(II) 12-metallacrown-4 complex based on a picoline hydroxamic acid resulted in the formation of the tetranuclear compounds which are the first examples of solely hydroxamate-based Cu(II) metallacrown complexes with a collapse of the metallamacrocyclic cavity.

引用

页码：6221 / 6227

页数：7

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