Polymer analysis by pyrolysis gas chromatography

被引:46
作者
Wang, FCY [1 ]
机构
[1] Dow Chem Co USA, Analyt Sci Lab, Midland, MI 48667 USA
关键词
pyrolysis; derivatization; GC; polymers;
D O I
10.1016/S0021-9673(98)01051-6
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Pyrolysis gas chromatography (Py-GC) has been an important technique in the qualitative and quantitative analysis of polymers for more than thirty years. Recent developments in Py-GC technology are mainly focused on pyrolysis operation and applications. In the former category, the focus is on the development of flexible pyrolysis instrumentation, "pre-" and "post-" pyrolysis derivatization and database creation/maintenance. In the application field, the development focused on kinetics of thermal degradation, structure determination and integrate techniques associated with pyrolysis to perform qualitative and quantitative analysis of low level additives in polymers. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:413 / 423
页数:11
相关论文
共 51 条
[1]   Studies of the thermal degradation of polysulfones by filament-pulse pyrolysis gas chromatography [J].
Almen, P ;
Ericsson, I .
POLYMER DEGRADATION AND STABILITY, 1995, 50 (02) :223-228
[2]   Database for organic sulfur compounds using GC-SCD method. Determination of sulfur containing compounds in straight run gas oils (SRGO) [J].
Andari, MK ;
Behbehani, H ;
Qabazard, H .
FUEL SCIENCE & TECHNOLOGY INTERNATIONAL, 1996, 14 (07) :897-908
[3]  
[Anonymous], PYROLYSIS GAS CHROMA
[4]   Kinetic measurements by pyrolysis-gas chromatography, and examples of their use in deducing mechanisms [J].
Bate, DM ;
Lehrle, RS .
POLYMER DEGRADATION AND STABILITY, 1996, 53 (01) :39-44
[5]   The thermal behaviour of some epoxy-acrylic polymers based on phenol and para-alkyl substituted phenols [J].
Cascaval, CN ;
Rosu, D ;
Agherghinei, I .
POLYMER DEGRADATION AND STABILITY, 1996, 52 (03) :253-257
[7]   QUANTITATIVE-ANALYSIS OF 2,6-DI-TERT-BUTYL-4-METHYLPHENOL(BUTYLATED-HYDROXYTOLUENE) ANTIOXIDANT IN A SOLVENT-FORMULATED LIQUID POLYCHLOROPRENE ADHESIVE AND IN CURED POLYCHLOROPRENE ADHESIVE FILMS [J].
FRANICH, RA ;
KROESE, HW ;
LANE, G .
ANALYST, 1995, 120 (07) :1927-1931
[8]   Pyrolysis gas chromatography mass spectrometry investigation of a thermally cured polymer [J].
Galipo, RC ;
Egan, WJ ;
Aust, JF ;
Myrick, ML ;
Morgan, SL .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1998, 45 (01) :23-40
[9]   THE DEGRADATION MECHANISM OF POLYISOBUTYLENE .2. CHARACTERIZATION OF THE PRODUCTS AND THE DEPENDENCE OF THEIR YIELDS ON SAMPLE THICKNESS PROVIDES DETAILED MECHANISTIC INFORMATION [J].
GRIMBLEY, MR ;
LEHRLE, RS .
POLYMER DEGRADATION AND STABILITY, 1995, 48 (03) :441-455
[10]   High-resolution pyrolysis gas chromatography with a movable reaction zone [J].
Hetper, J ;
Sobera, M .
JOURNAL OF CHROMATOGRAPHY A, 1997, 776 (02) :337-341