Crystal and electronic structure and physical properties of Ni5P4

被引：9

作者：

Babizhetskyy, V. ^{[1
]}

Kotur, B. ^{[1
]}

Oryshchyn, S. ^{[1
]}

Zheng, C. ^{[2
]}

Kneidinger, F. ^{[3
]}

Leber, L. ^{[3
]}

Simson, C. ^{[3
]}

Bauer, E. ^{[3
]}

Michor, H. ^{[3
]}

机构：

[1] Ivan Franko Natl Univ Lviv, Dept Inorgan Chem, UA-79005 Lvov, Ukraine

[2] No Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA

[3] Vienna Univ Technol, Inst Solid State Phys, A-1040 Vienna, Austria

来源：

SOLID STATE COMMUNICATIONS | 2013年 / 164卷

基金：

奥地利科学基金会;

关键词：

Binary nickel-phosphorus compound; Magnetic behavior; Electrical resistivity; Specific heat; SUPERCONDUCTOR;

D O I：

10.1016/j.ssc.2013.03.022

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Ni5P4 crystallizes in hexagonal symmetry, space group P6(3)mc, and adopts its own non-centrosymmetric structure type with lattice constants a=6.78982(4), c=10.98679(7) angstrom according to x-ray powder diffraction. Calorimetric, magnetic and transport studies of Ni5P4 reveal a Pauli-paramagnetic, normal metallic behavior down to 380 mK. The experimental value of the electronic Sommerfeld coefficient gamma=13.2 mJ/mol K-2) as well as ab initio electronic structure calculations indicate a moderate electronic density of states at the Fermi level situated near the upper edge of essentially filled d-bands. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：1 / 5

页数：5

共 18 条

[1]

Akselrud L.G., 1993, MAT SCI FORUM, V133-136, P335, DOI [10.4028/www.scientific.net/msf.133-136.335, DOI 10.4028/WWW.SCIENTIFIC.NET/MSF.133-136.335]

[2] EXPLICIT, 1ST-PRINCIPLES TIGHT-BINDING THEORY [J].

ANDERSEN, OK ;

JEPSEN, O .

PHYSICAL REVIEW LETTERS, 1984, 53 (27) :2571-2574

[3] AN EXTENDED HUCKEL THEORY .I. HYDROCARBONS [J].

HOFFMANN, R .

JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (06) :1397-&

[4] Iron-based layered superconductor: LaOFeP [J].

Kamihara, Yoichi ;

Hiramatsu, Hidenori ;

Hirano, Masahiro ;

Kawamura, Ryuto ;

Yanagi, Hiroshi ;

Kamiya, Toshio ;

Hosono, Hideo .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (31) :10012-10013

[5] Controllable Synthesis of a Monophase Nickel Phosphide/Carbon (Ni5P4/C) Composite Electrode via Wet-Chemistry and a Solid-State Reaction for the Anode in Lithium Secondary Batteries [J].

Lu, Yi ;

Tu, Jiang-Ping ;

Xiong, Qin-Qin ;

Xiang, Jia-Yuan ;

Mai, Yong-Jin ;

Zhang, Jun ;

Qiao, Yan-Qiang ;

Wang, Xiu-Li ;

Gu, Chang-Dong ;

Mao, Scott X. .

ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (18) :3927-3935

[6]

Massalski T.B., 1990, BINARY ALLOYS PHASE, V2nd

[7]

Nash P., 1991, PHASE DIAGRAMS BINAR

[8]

Oryshchyn S., 2004, INORG MATER, V40, P450

[9] Crystal structure of HT-Ni5P2 and reinvestigation of isotypic Ni5As2 [J].

Oryshchyn, Stepan ;

Babizhetskyy, Volodymyr ;

Zhak, Olga ;

Stoyko, Stanislav ;

Guerin, Roland ;

Simon, Arndt .

INTERMETALLICS, 2011, 19 (07) :1041-1046

[10] A new investigation of the system Ni-P [J].

Schmetterer, Clemens ;

Vizdal, Jiri ;

Ipser, Herbert .

INTERMETALLICS, 2009, 17 (10) :826-834

← 1 2 →