A formal synthesis of (±) parvifoline by manganese(III)-based oxidative arylation of ketones

被引：15

作者：

Bhowmik, DR ^{[1
]}

Venkateswaran, RV ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Organ Chem, Calcutta 700032, W Bengal, India

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 41期

关键词：

oxidative free-radical cyclization; Grob fragmentation; benzocyclooctene;

D O I：

10.1016/S0040-4039(99)01521-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A short, formal synthesis of the phenolic sesquiterpene (+/-) parvifoline 1 is described involving manganese(III)based oxidative arylation of the ketone 9 as the key step. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：7431 / 7433

页数：3

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