Active Molybdenum-Based Anode for Dehydrogenative Coupling Reactions

被引：50

作者：

Beil, Sebastian B. ^{[1
,2
]}

Mueller, Timo ^{[1
]}

Sillart, Sydney B. ^{[1
]}

Franzmann, Peter ^{[1
]}

Bomm, Alexander ^{[3
]}

Holtkamp, Michael ^{[4
]}

Karst, Uwe ^{[4
]}

Schade, Wolfgang ^{[3
]}

Waldvogel, Siegfried R. ^{[1
,2
]}

机构：

[1] Johannes Gutenberg Univ Mainz, Inst Organ Chem, Duesbergweg 10-14, D-55128 Mainz, Germany

[2] Grad Sch Excellence, Mat Sci Mainz MAINZ, Staudingerweg 9, D-55128 Mainz, Germany

[3] Fraunhofer Heinrich Hertz Inst, Abt Faseropt Sensorsyst, Stollen 19H, D-38640 Goslar, Germany

[4] Univ Munster, Inst Inorgan & Analyt Chem, Corrensstr 30, D-48149 Munster, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 09期

关键词：

anode; arene coupling; electrochemistry; molybdenum; oxidative coupling; SINGLE AROMATIC SUBSTRATE; N BOND FORMATION; DIARYLIODONIUM(III) SALTS; ORGANIC-COMPOUNDS; ALKALI SOLUTION; LIGNIN; ELECTRODES; REDUCTION; DEGRADATION; SELECTIVITY;

D O I：

10.1002/anie.201712718

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new and powerful active anode system that can be operated in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) has been discovered. In HFIP the molybdenum anode forms a compact, conductive, and electroactive layer of higher-valent molybdenum species. This system can replace powerful but stoichiometrically required Mo-V reagents for the dehydrogenative coupling of aryls. This electrolytic reaction is more sustainable and allows the conversion of a broad scope of activated arenes.

引用

页码：2450 / 2454

页数：5

共 61 条

[41] GALVANOSTATIC ELECTROCHEMICAL REDUCTION OF PENTOSES
PISZCZEK, L
GIELDON, K
WOJTKOWIAK, SZ
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1992, 22 (11) : 1055 - 1059
[42] ELECTROLYTIC REDUCTION OF ORGANIC COMPOUNDS
POPP, FD
SCHULTZ, HP
[J]. CHEMICAL REVIEWS, 1962, 62 (01) : 19 - +
[43] SCHAFER HJ, 1987, TOP CURR CHEM, V142, P101
[44] Treatment of black liquor (BL) by adsorption on AE resins and a subsequent electrochemical degradation of BL to obtain vanillin
Schmitt, Dominik
Regenbrecht, Carolin
Schubert, Moritz
Schollmeyer, Dieter
Waldvogel, Siegfried R.
[J]. HOLZFORSCHUNG, 2017, 71 (01) : 35 - 41
[45] Highly selective generation of vanillin by anodic degradation of lignin: a combined approach of electrochemistry and product isolation by adsorption
Schmitt, Dominik
Regenbrecht, Carolin
Hartmer, Marius
Stecker, Florian
Waldvogel, Siegfried R.
[J]. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2015, 11 : 473 - 480
[46] Schubert M., 2014, ANGEW CHEM, V126, P2527
[47] Schubert M., 2016, ANGEW CHEM, V128, P1168, DOI DOI 10.1002/ANGE.201508035
[48] MoV Reagents in Organic Synthesis
Schubert, Moritz
Waldvogel, Siegfried R.
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 2016 (11) : 1921 - 1936
[49] Over-Oxidation as the Key Step in the Mechanism of the MoCl5-Mediated Dehydrogenative Coupling of Arenes
Schubert, Moritz
Franzmann, Peter
von Leupoldt, Anica Wuensche
Koszinowski, Konrad
Heinze, Katja
Waldvogel, Siegfried R.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (03) : 1156 - 1159
[50] Powerful Fluoroalkoxy Molybdenum(V) Reagent for Selective Oxidative Arene Coupling Reaction
Schubert, Moritz
Leppin, Jana
Wehming, Kathrin
Schollmeyer, Dieter
Heinze, Katja
Waldvogel, Siegfried R.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (09) : 2494 - 2497

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