Metal ion directed metal-organic rotaxane frameworks with intrinsic features of self-penetration and interpenetration

被引：37

作者：

Liang, Jun ^{[1
]}

Wang, Xin-Long ^{[1
]}

Jiao, Yan-Qing ^{[1
]}

Qin, Chao ^{[1
]}

Shao, Kui-Zhan ^{[1
]}

Su, Zhong-Min ^{[1
]}

Wu, Qing-Yin ^{[2
]}

机构：

[1] NE Normal Univ, Inst Funct Mat Chem, Key Lab Polyoxometalate Sci, Minist Educ, Changchun 130024, Jilin, Peoples R China

[2] Zhejiang Univ, Dept Chem, Hangchow, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 76期

关键词：

DYNAMIC COMBINATORIAL CHEMISTRY; BOND-VALENCE PARAMETERS; CROWN-ETHER WHEELS; INCORPORATING CUCURBITURIL; INTERLOCKED COMPONENTS; HELICAL POLYROTAXANE; LIGANDS; MOLECULES; LIBRARIES; AXLES;

D O I：

10.1039/c3cc43990a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three novel self-catenated 4-connected uninodal (6(5).8)-mok metal-organic rotaxane frameworks (MORFs) containing cucurbit[6]uril were constructed from the in situ trans/cis-configuration (1:1) of rotaxanes by taking advantage of a d(10) metal ion directed synthesis. It was revealed that the effect of hydrogen bonds and pi-pi stacking interactions play significant roles in the self-assembly process.

引用

页码：8555 / 8557

页数：3

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