New rhodacyclopentane with phenylvinylidene substituents, mer-[Rh{CH2C(=CHPh)C(=CHPh)CH2}Cl(PMe3)(3)]. Structure and formation through concerted cycloaddition of phenylallene molecules to [RhCl(PMe3)(3)]

被引：2

作者：

Osakada, K

Choi, JC

Sarai, S

Koizumi, T

Yamamoto, T

机构：

[1] Res. Lab. of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 14期

关键词：

D O I：

10.1039/a701859b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[RhCl(PMe3)(3)] reacts with an excess of phenylallene to give new rhodacyclopentane, mer-[Rh{CH2C(=CHPh)C(=CHPh)CH2}Cl(PMe3)(3)] 1, which is not obtained via the reaction of [RhCl(eta(2)-CH2=C=CHPh)(PMe3)(3)] 2 with phenylallene.

引用

页码：1313 / 1314

页数：2

共 17 条

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