Facile synthesis of SnO2-ZnO core-shell nanowires for enhanced ethanol-sensing performance

被引:53
作者
Dang Thi Thanh Le [1 ]
Do Dang Trung [1 ]
Nguyen Duc Chinh [1 ]
Bui Thi Thanh Binh [1 ,2 ]
Hoang Si Hong [3 ]
Nguyen Van Duy [1 ]
Nguyen Duc Hoa [1 ]
Nguyen Van Hieu [1 ]
机构
[1] Hanoi Univ Sci & Technol, Int Training Inst Mat Sci, Hanoi, Vietnam
[2] Hanoi Univ Sci & Technol, Sch Chem Engn, Hanoi, Vietnam
[3] Hanoi Univ Sci & Technol, Sch Elect Engn, Hanoi, Vietnam
关键词
SnO2-ZnO; Grainy core-shell; Nanowire; Ethanol sensor; LOW-TEMPERATURE PHOTOLUMINESCENCE; SELECTIVE DETECTION;
D O I
10.1016/j.cap.2013.06.024
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The design of core-shell heteronanostructures is powerful tool to control both the gas selectivity and the sensitivity due to their hybrid properties. In this work, the SnO2-ZnO core-shell nanowires (NWs) were fabricated via two-step process comprising the thermal evaporation of the single crystalline SnO2 NWs core and the spray-coating of the grainy polycrystalline ZnO shell for enhanced ethanol sensing performance. The as-obtained products were investigated by X-ray diffraction, scanning electron microscopy, and photoluminescence. The ethanol gas-sensing properties of pristine SnO2 and ZnO-SnO2 core-shell NW sensors were studied and compared. The gas response to 500 ppm ethanol of the core-shell NW sensor increased to 33.84, which was 12.5-fold higher than that of the pristine SnO2 NW sensor. The selectivity of the core-shell NW sensor also improved. The response to 100 ppm ethanol was about 14.1, whereas the response to 100 ppm liquefied petroleum gas, NH3, H-2, and CO was smaller, and ranged from 2.5 to 5.3. This indicates that the core-shell heterostructures have great potential for use as gas sensing materials. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:1637 / 1642
页数:6
相关论文
共 40 条
[1]   Gas sensing properties of defect-controlled ZnO-nanowire gas sensor [J].
Ahn, M. -W. ;
Park, K. -S. ;
Heo, J. -H. ;
Park, J. -G. ;
Kim, D. -W. ;
Choi, K. J. ;
Lee, J. -H. ;
Hong, S. -H. .
APPLIED PHYSICS LETTERS, 2008, 93 (26)
[2]   The surface and materials science of tin oxide [J].
Batzill, M ;
Diebold, U .
PROGRESS IN SURFACE SCIENCE, 2005, 79 (2-4) :47-154
[3]   Atomic Layer Deposition of Al2O3 onto Sn-Doped In2O3: Absence of Self-Limited Adsorption during Initial Growth by Oxygen Diffusion from the Substrate and Band Offset Modification by Fermi Level Pinning in Al2O3 [J].
Bayer, Thorsten J. M. ;
Wachau, Andre ;
Fuchs, Anne ;
Deuermeier, Jonas ;
Klein, Andreas .
CHEMISTRY OF MATERIALS, 2012, 24 (23) :4503-4510
[4]   Synthesis of SnO2-ZnO core-shell nanofibers via a novel two-step process and their gas sensing properties [J].
Choi, Sun-Woo ;
Park, Jae Young ;
Kim, Sang Sub .
NANOTECHNOLOGY, 2009, 20 (46)
[5]   Selective detection of carbon dioxide using LaOCl-functionalized SnO2 nanowires for air-quality monitoring [J].
Do Dang Trung ;
Le Duc Toan ;
Hoang Si Hong ;
Tran Dai Lam ;
Tran Trung ;
Nguyen Van Hieu .
TALANTA, 2012, 88 :152-159
[6]   Low-temperature chemical solution route for ZnO based sulfide coaxial nanocables: general synthesis and gas sensor application [J].
Du, Ning ;
Zhang, Hui ;
Chen, Bingdi ;
Wu, Jianbo ;
Yang, Deren .
NANOTECHNOLOGY, 2007, 18 (11)
[7]   On the selectivity of nanostructured semiconductor gas sensors [J].
Heszler, P. ;
Ionescu, R. ;
Llobet, E. ;
Reyes, L. F. ;
Smulko, J. M. ;
Kish, L. B. .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2007, 244 (11) :4331-4335
[8]   A facile thermal evaporation route for large-area synthesis of tin oxide nanowires: Characterizations and their use for liquid petroleum gas sensor [J].
Hieu, Nguyen Van ;
Loan, Le Thi Ngoc ;
Khoang, Nguyen Duc ;
Minh, Nguyen Tuan ;
Viet, Do Thanh ;
Minh, Do Cong ;
Trung, Tran ;
Chien, Nguyen Duc .
CURRENT APPLIED PHYSICS, 2010, 10 (02) :636-641
[9]   Synthesis and gas sensing characteristics of highly crystalline ZnO-SnO2 core-shell nanowires [J].
Hwang, In-Sung ;
Kim, Sun-Jung ;
Choi, Joong-Ki ;
Choi, Jaewan ;
Ji, Hyunjin ;
Kim, Gyu-Tae ;
Cao, Guozhong ;
Lee, Jong-Heun .
SENSORS AND ACTUATORS B-CHEMICAL, 2010, 148 (02) :595-600
[10]   Highly conductive coaxial SnO2-In2O3 heterostructured nanowires for li ion battery electrodes [J].
Kim, Dong-Wan ;
Hwang, In-Sung ;
Kwon, S. Joon ;
Kang, Hae-Yong ;
Park, Kyung-Soo ;
Choi, Young-Jin ;
Choi, Kyoung-Jin ;
Park, Jae-Gwan .
NANO LETTERS, 2007, 7 (10) :3041-3045