All Five Forms of Cytosine Revealed in the Gas Phase

被引：68

作者：

Alonso, Jose L. ^{[1
]}

Vaquero, Vanesa ^{[1
]}

Pena, Isabel ^{[1
]}

Lopez, Juan C. ^{[1
]}

Mata, Santiago ^{[1
]}

Caminati, Walther ^{[1
]}

机构：

[1] Univ Valladolid, GEM, E-47005 Valladolid, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 08期

关键词：

cytosine; laser ablation; microwave spectroscopy; supersonic jets; tautomerism; QUADRUPOLE COUPLING-CONSTANTS; MICROWAVE SPECTROSCOPY; TAUTOMERS; SPECTRUM; ACID; N-14; BIOMOLECULES; CONFORMERS; DYNAMICS; ROTATION;

D O I：

10.1002/anie.201207744

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Give me five! All five tautomers and conformers of cytosine were characterized in the gas phase by laser ablation molecular beam Fourier transform microwave spectroscopy. The spectra were assigned unambiguously on the basis of the hyperfine structure due to the three 14N nuclei (see picture; N blue, O red). The relative energies of the identified species were estimated from the relative intensities of the spectra. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2331 / 2334

页数：4

共 35 条

[1] Rotational Spectral Signatures of Four Tautomers of Guanine [J].