Lanthanides Mediated Oxidative Cross Coupling of Benzylalcohol and Various Amines to Form Corresponding Imines

被引：2

作者：

Bhattacharjee, Jayeeta ^{[1
]}

Sachdeva, Mitali ^{[1
]}

Panda, Tarun K. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Hyderabad 502285, Telangana, India

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 17期

关键词：

Lanthanides; Alcohols; Cross-coupling; Imines; Catalysis; AEROBIC OXIDATION; BETA-ALKYLATION; N-ALKYLATION; ALCOHOLS; COMPLEXES; RUTHENIUM; HYDROAMINATION; MILD; HYDROGENATION; REACTIVITY;

D O I：

10.1002/zaac.201600201

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein, a new and efficient approach towards the oxidative cross-coupling of benzylalcohol and various aromatic amines to form corresponding imines with high degree conversion (similar to 80%) and chemo-selectivity using lanthanide salts as pre-catalysts is presented. The catalyzed oxidative cross-coupling reaction using La(NO3)(3)center dot 6H(2)O as pre-catalyst displayed a broad substrate scope. The reaction afforded various substituted imines from the reaction of benzylalcohol with ample variety of amines in good yields.

引用

页码：937 / 940

页数：4

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