Enhancing the conductivity of isotactic polypropylene/polyethylene/carbon black composites by oscillatory shear

被引:2
作者
Huang, Shilin [1 ]
Liu, Zhengying [1 ]
Zheng, Shaodi [1 ]
Yang, Mingbo [1 ]
机构
[1] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu 610065, Sichuan, Peoples R China
基金
中国国家自然科学基金;
关键词
Conductivity; Composite; Rheology; Shear; Morphology; FILLED POLYMER BLENDS; ELECTRICAL-CONDUCTIVITY; CARBON-BLACK; PERCOLATION; MORPHOLOGY; POLYETHYLENE; COALESCENCE; NETWORK; BREAKUP;
D O I
10.1007/s00396-013-3074-y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of oscillatory shear on the conductivity of the isotactic polypropylene/polyethylene/carbon black composites is studied. It is found that the oscillatory shear under high strain amplitude can enhance the conductivity of the ternary composites with a HDPE/CB concentration in the percolation region. This is related to the fact that the high-strain oscillatory shear can improve the continuity of the conductive HDPE/CB phase in the composites. This finding has not been previously reported, and it may be used in industry to improve the conductivity of the ternary conductive composites with a low filler loading.
引用
收藏
页码:3005 / 3011
页数:7
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