Novel and Chemoselective Dehydrogenation of 3,4-Dihydropyrimidin-2(1H)-ones with 1,4-Bis(triphenylphosphonium)-2-butene Peroxodisulfate

被引：3

作者：

Gorjizadeh, Maryam ^{[1
]}

机构：

[1] Islamic Azad Univ, Dept Chem, Shoushtar Branch, Shoushtar 6451741117, Iran

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2013年 / 34卷 / 06期

关键词：

Dehydrogenation; Pyrimidin-2(1H)-ones; 3,4-Dihydropyrimidin-2(1H)-ones; 1,4-Bis(triphenylphosphonium)-2-butene peroxodisulfate; ONE-POT SYNTHESIS; EFFICIENT REAGENT; BIGINELLI-TYPE; OXIDATION; PEROXYDISULFATE; PROTOCOL;

D O I：

10.5012/bkcs.2013.34.6.1751

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3,4-Dihydropyrimidin-2(1H)-ones were efficiently converted into the corresponding pyrimidin-2(1H)-ones in high yields within a short period of time on treatment with aqueous acetonitrile using 1,4-bis(triphenyl phosphonium)-2-butene peroxodisulfate. Chemoselective oxidation of 3,4-dihydropyrimidin in the presence of other oxidizable functional groups was also achieved by this reagent.

引用

页码：1751 / 1754

页数：4

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