Synthesis of bridgehead-functionalized triptycene quinones via Lewis acid-promoted Diets-Alder reaction of 9-acyloxyanthracenes

被引：13

作者：

Matsumoto, Kenji ^{[1
]}

Nakano, Rina ^{[1
]}

Hirokane, Tsukasa ^{[1
]}

Yoshida, Masahiro ^{[1
]}

机构：

[1] Tokushima Bunri Univ, Fac Pharmaceut Sci, Yamashiro, Tokushima 7708514, Japan

来源：

TETRAHEDRON LETTERS | 2019年 / 60卷 / 14期

关键词：

Triptycene; Triptycene quinone; Diels-Alder reaction; Anthracene; Lewis acid; CATALYZED DIELS-ALDER; 9-SUBSTITUTED ANTHRACENES; DERIVATIVES; IPTYCENES; DESIGN;

D O I：

10.1016/j.tetlet.2019.03.001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Herein, we show that bridgehead-functionalized triptycene quinones can be rapidly and conveniently prepared in good to high yields by Lewis acid-catalyzed cycloaddition of 1,4-benzoquinones and 1,4-naphthoquinones to 9-acyloxyanthracenes and probe the substrate scope of this transformation. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页码：975 / 978

页数：4

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