Synthesis and magnetic property of a one-dimensional 3d-4f heterometallic triple-chain complex

被引：2

作者：

Bai, Yue-Ling ^{[1
]}

Xing, Feifei ^{[1
]}

Zhu, Shourong ^{[1
]}

Tao, Jun ^{[2
]}

机构：

[1] Shanghai Univ, Coll Sci, Dept Chem, Shanghai 200444, Peoples R China

[2] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Dept Chem, Xiamen 361005, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 20卷

基金：

中国国家自然科学基金;

关键词：

Heterometallic complex; Triple-chain; Crystal structure; Magnetic properties; II/GD-III COUPLE; INTRINSIC PROPERTY; IONS; LN; FERROMAGNETISM; FAMILY; TB; GD;

D O I：

10.1016/j.inoche.2012.02.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A heterometallic triple-chain complex [CuTb2(mal)(4)(H2O)(6)]center dot 2H(2)O (CuTb2, H(2)mal = D-malic acid) and its isomorphous CuY2 and ZnTb2 have been prepared and characterized, whose magnetic properties are studied by comparison with its analogues. The results indicate that the Cu center dot center dot center dot Tb interactions in CuTb2 are antiferromagnetic. Published by Elsevier B.V.

引用

页码：50 / 53

页数：4

共 29 条

[1] Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals [J].

Benelli, C ;

Gatteschi, D .

CHEMICAL REVIEWS, 2002, 102 (06) :2369-2387

[2]

Casey A.T., 1976, Theory and Applications of Molecular Paramagnetism, P135

[3] Solvothermal synthesis, structure and properties of a new 3-D Cu(I)-Gd(III) heterometallic coordination framework [J].

Chen, Man-Sheng ;

Deng, Yi-Fang ;

Zhang, Chun-Hua ;

Kuang, Dai-Zhi ;

Nie, Xue ;

Liu, Yang .

INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (06) :944-947

[4] Lanthanide-transition-metal sandwich framework comprising {Cu} cluster pillars and layered networks of {Er36} wheels (vol 45, pg 73, 2006) [J].

Cheng, JW ;

Zhang, J ;

Zheng, ST ;

Zhang, MB ;

Yang, GY .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (05) :689-689

[5] Is ferromagnetism an intrinsic property of the CuII/GdIII couple?: 1.: Structures and magnetic properties of two novel dinuclear complexes with a μ-phenolato-μ-oximato (Cu,Gd) core [J].

Costes, JP ;

Dahan, F ;

Dupuis, A ;

Laurent, JP .

INORGANIC CHEMISTRY, 2000, 39 (02) :169-173

[6] Heterodinuclear Cu-Tb single-molecule magnet [J].

Costes, JP ;

Dahan, F ;

Wernsdorfer, W .

INORGANIC CHEMISTRY, 2006, 45 (01) :5-7

[7] Is ferromagnetism an intrinsic property of the CuII/GdIII couple?: 2.: Structures and magnetic properties of novel trinuclear complexes with μ-phenolato-μ-oximato (Cu-Ln-Cu) cores (Ln = La, Ce, Gd) [J].

Costes, JP ;

Dahan, F ;

Dupuis, A .

INORGANIC CHEMISTRY, 2000, 39 (26) :5994-6000

[8]

Doble DMJ, 1999, ANGEW CHEM INT EDIT, V38, P1915, DOI 10.1002/(SICI)1521-3773(19990712)38:13/14<1915::AID-ANIE1915>3.0.CO

[9]

2-L

[10] One dimensional 3d-4f heterometallic compounds:: Synthesis, structure and magnetic properties [J].

Figuerola, Albert ;

Ribas, Joan ;

Solans, Xavier ;

Font-Bardia, Merce ;

Maestro, Miguel ;

Diaz, Carmen .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (09) :1846-1852

← 1 2 3 →