Scope of the Suzuki-Miyaura Cross-Coupling Reaction of Potassium Trifluoroboratoketohomoenolates

被引：40
|
作者：
Molander, Gary A. [1 ]
Jean-Gerard, Ludivine [1 ]
机构：
[1] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 03期
基金：
美国国家卫生研究院;
关键词：
CATALYZED BETA-BORATION; ZINC HOMOENOLATE; ALPHA; BETA-UNSATURATED KETONES; CARBONYL-COMPOUNDS; ARYL CHLORIDES; ESTERS; CHEMISTRY; ACYLATION; BIS(PINACOLATO)DIBORON; SILOXYCYCLOPROPANES;
D O I：
10.1021/jo802453m
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Potassium trifluoroboratoketohomoenolates were prepared in good yields from either the corresponding alpha,beta-unsaturated compounds or methyl ketones. These organoboron reagents were effectively cross-coupled with various aryl and heteroaryl chlorides.
引用
收藏
页码：1297 / 1303
页数：7
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