A spin-crossover ionic liquid from the cationic iron(III) Schiff base complex

被引：44

作者：

Okuhata, Megumi ^{[1
]}

Funasako, Yusuke ^{[1
]}

Takahashi, Kazuyuki ^{[1
]}

Mochida, Tomoyuki ^{[1
]}

机构：

[1] Kobe Univ, Dept Chem, Grad Sch Sci, Nada, Hyogo 6578501, Japan

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 69期

关键词：

MAGNETIC-PROPERTIES; THERMAL-PROPERTIES; CRYSTAL-STRUCTURES; DYNAMICS; ADDUCTS; SALTS;

D O I：

10.1039/c3cc44199g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A thermochromic magnetic ionic liquid containing a cationic iron(III) Schiff-base complex has been developed, whose color and magnetic moment change with temperature because of spin crossover in the liquid state. This spin-crossover behavior closely resembles that of a solid having the same cation.

引用

页码：7662 / 7664

页数：3

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