Orderly Nanopatterned Indium Tin Oxide Electrode Combined with Atomic-Layer-Deposited Metal Oxide Interlayer for Inverted Organic Solar Cells

被引:4
作者
Lin, Zhenhua [1 ,2 ]
Zhu, Mei [3 ]
Chang, Jingjing [2 ,4 ]
Jiang, Changyun [2 ]
Zhang, Jie [2 ]
Wu, Jishan [2 ,4 ]
Choi, Wee Kiong [1 ]
Zhu, Chunxiang [1 ]
机构
[1] Natl Univ Singapore, Dept Elect & Comp Engn, Singapore 119260, Singapore
[2] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore
[3] Natl Univ Singapore, NUS Grad Sch Integrat Sci & Engn, Singapore 117456, Singapore
[4] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
关键词
light trapping effect; nanostructures; organic solar cells; oxides; thin films; POLYMER PHOTOVOLTAIC CELLS; EFFICIENCY ENHANCEMENT; HIGHLY EFFICIENT; BROAD-BAND;
D O I
10.1002/ente.201500051
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this work, well-ordered periodic nanogroove structures are constructed on the surfaces of indium tin oxide (ITO) substrates through a simple and cost-effective patterning method, laser interference lithography (LIL). By using the nanopatterned ITO electrodes coated conformally with metal oxide thin films as the electron-selective interlayer (ESL) fabricated by low-temperature atomic layer deposition (ALD), periodically nanostructured cathode-active-layer interfaces are formed in the inverted organic solar cells (OSCs). Compared with a planar-ITO cathode, a nanopatterned ITO cathode with 30nm high nanogrooves leads to considerably improved short-circuit current and power conversion efficiency for poly(3-hexylthiophene)/[6,6]-phenyl-C61-butyric acid methyl ester (P3HT/PCBM) based cells. The improvement in the photocurrent is caused by enhanced light absorption and improved charge-carrier generation in the devices with nanostructured cathode-active-layer interfaces.
引用
收藏
页码:906 / 912
页数:7
相关论文
共 34 条
[1]  
Atwater HA, 2010, NAT MATER, V9, P205, DOI [10.1038/NMAT2629, 10.1038/nmat2629]
[2]   A low-bandgap poly(2,7-carbazole) derivative for use in high-performance solar cells [J].
Blouin, Nicolas ;
Michaud, Alexandre ;
Leclerc, Mario .
ADVANCED MATERIALS, 2007, 19 (17) :2295-+
[3]   Efficient and air-stable plastics-based polymer solar cells enabled by atomic layer deposition [J].
Chang, Chih-Yu ;
Tsai, Feng-Yu .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (15) :5710-5715
[4]   TiOx/Al bilayer as cathode buffer layer for inverted organic solar cell [J].
Chang, Jingjing ;
Kam, Zhi Ming ;
Lin, Zhenhua ;
Zhu, Chunxiang ;
Zhang, Jie ;
Wu, Jishan .
APPLIED PHYSICS LETTERS, 2013, 103 (17)
[5]   Solution-Processed LiF-Doped ZnO Films for High Performance Low Temperature Field Effect Transistors and Inverted Solar Cells [J].
Chang, Jingjing ;
Lin, Zhenhua ;
Zhu, Chunxiang ;
Chi, Chunyan ;
Zhang, Jie ;
Wu, Jishan .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (14) :6687-6693
[6]   Polymer solar cells with enhanced open-circuit voltage and efficiency [J].
Chen, Hsiang-Yu ;
Hou, Jianhui ;
Zhang, Shaoqing ;
Liang, Yongye ;
Yang, Guanwen ;
Yang, Yang ;
Yu, Luping ;
Wu, Yue ;
Li, Gang .
NATURE PHOTONICS, 2009, 3 (11) :649-653
[7]   Recent Progress in Polymer Solar Cells: Manipulation of Polymer: Fullerene Morphology and the Formation of Efficient Inverted Polymer Solar Cells [J].
Chen, Li-Min ;
Hong, Ziruo ;
Li, Gang ;
Yang, Yang .
ADVANCED MATERIALS, 2009, 21 (14-15) :1434-1449
[8]   Large scale two-dimensional nanobowl array high efficiency polymer solar cell [J].
Chen, Szu-Ying ;
Yen, Yu-Ting ;
Chen, Yi-Yang ;
Hsu, Chain-Shu ;
Chueh, Yu-Lun ;
Chen, Lih-Juann .
RSC ADVANCES, 2012, 2 (04) :1314-1317
[9]   Extremely low temperature growth of ZnO by atomic layer deposition [J].
Guziewicz, E. ;
Kowalik, I. A. ;
Godlewski, M. ;
Kopalko, K. ;
Osinniy, V. ;
Wojcik, A. ;
Yatsunenko, S. ;
Lusakowska, E. ;
Paszkowicz, W. ;
Guziewicz, M. .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (03)
[10]  
He ZC, 2012, NAT PHOTONICS, V6, P591, DOI [10.1038/NPHOTON.2012.190, 10.1038/nphoton.2012.190]