Efficient solvent-free aminolysis of epoxides under (C4H12N2)2[BiCl6]Cl•H2O catalysis

被引：22
作者：
Lu, Hong-Fei [1 ]
Sun, Lei-Lei [1 ]
Le, Wen-Jun [1 ]
Yang, Fei-Fei [1 ]
Zhou, Jun-Tao [1 ]
Gao, Yu-Hua [1 ]
机构：
[1] Jiangsu Univ Sci & Technol, Sch Biol & Chem Engn, Zhenjiang 212003, Peoples R China
来源：
TETRAHEDRON LETTERS | 2012年 / 53卷 / 33期
关键词：
Epoxides; Amines; Aminolysis; beta-Amino alcohols; RING-OPENING REACTION; ASYMMETRIC AMINOHYDROXYLATION; ALCOHOLS; TRIBUTYLPHOSPHINE; DERIVATIVES; INHIBITORS; CLEAVAGE; ANILINES; AMINES;
D O I：
10.1016/j.tetlet.2012.05.079
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient and rapid procedure for ring opening of various epoxides with aromatic, aliphatic and heterocyclic amines is developed at room temperature under solvent-free conditions in the presence of (C4H12N2)(2)[BiCl6]Cl center dot H2O (1 mol %). This catalyst can be reused several times without losing of its activity. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4267 / 4272
页数：6
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