SBA-15 mesoporous silica as a super insulating material

被引:23
作者
Belmoujahid, Y. [1 ]
Bonne, M. [1 ]
Scudeller, Y. [2 ]
Schleich, D. [2 ]
Grohens, Y. [3 ]
Lebeau, B. [1 ]
机构
[1] Univ Haute Alsace, Univ Strasbourg, Equipe Mat Poros Controlee MPC, ENSCMu,IS2M,CNRS,UMR 7361, 3 Bis Rue Alfred Werner, F-68093 Mulhouse, France
[2] Univ Nantes, Inst Mat Jean Rouxel, Equipe Ingn Mat & Metal, CNRS,UMR 6502, F-44306 Nantes 3, France
[3] Univ Bretagne Sud, Equipe Polymeres & Composites, Lab Ingn Mat Bretagne, EA 4250, F-56321 Lorient, France
关键词
THERMAL-CONDUCTIVITY; PARTICLES; CATALYSTS; ADSORPTION; STABILITY; AEROGELS; SOLIDS; PORES;
D O I
10.1140/epjst/e2015-02498-3
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The thermal insulation behavior of ordered mesoporous silica SBA-15 aggregates heat treated at 300 C-a similar to was studied. An important decrease in the effective thermal conductivity according to the increase of the apparent density was observed. A thermal conductivity value less than 25 mW.m(-1).K-1 was reached during the compaction phenomenon. Results of thermal conductivity were correlated to the electron microscopy observations and physicochemical data (X-ray diffraction, adsorption/desorption of nitrogen volumetric measurements). These thermal properties make these materials very promising for thermal insulation applications, especially with values inferior to the thermal conductivity of air.
引用
收藏
页码:1775 / 1785
页数:11
相关论文
共 32 条
[1]   Thermal conductivity of monolithic assemblies of SBA-15 ordered mesoporous silica particles [J].
Belmoujahid, Yassine ;
Bonne, Magali ;
Scudeller, Yves ;
Schleich, Donald ;
Grohens, Yves ;
Lebeau, Benedicte .
MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 201 :124-133
[2]   Thermal conductivity of heat treated mesoporous silica particles [J].
Bippus, Laurent ;
Jaber, Maguy ;
Lebeau, Benedicte ;
Schleich, Donald ;
Scudeller, Yves .
MICROPOROUS AND MESOPOROUS MATERIALS, 2014, 190 :109-116
[3]   A meso-macro compartmentalized bioreactor obtained through silicalization of "green'' double emulsions: W/O/W and W/SLNs/W [J].
Blin, Jean-Luc ;
Jacoby, Jonathan ;
Kim, Sanghoon ;
Stebe, Marie-Jose ;
Canilho, Nadia ;
Pasc, Andreea .
CHEMICAL COMMUNICATIONS, 2014, 50 (80) :11871-11874
[4]   STUDIES ON PORE SYSTEMS IN CATALYSTS .13. PORE DISTRIBUTIONS FROM DESORPTION BRANCH OF A NITROGEN SORPTION ISOTHERM IN CASE OF CYLINDRICAL PORES .B. APPLICATIONS [J].
BROEKHOFF, JC ;
DEBOER, JH .
JOURNAL OF CATALYSIS, 1968, 10 (04) :377-+
[5]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[6]   Improvement of uncooled infrared imaging detector by using mesoporous silica as a thermal isolation layer [J].
Choi, Sun Gyu ;
Ha, Tae-Jung ;
Yu, Byoung-Gon ;
Jaung, Seung Pil ;
Kwon, Ohmyoung ;
Park, Hyung-Ho .
CERAMICS INTERNATIONAL, 2008, 34 (04) :833-836
[7]   Thermal conductivity of cubic and hexagonal mesoporous silica thin films [J].
Coquil, Thomas ;
Richman, Erik K. ;
Hutchinson, Neal J. ;
Tolbert, Sarah H. ;
Pilon, Laurent .
JOURNAL OF APPLIED PHYSICS, 2009, 106 (03)
[8]   Oxidative dehydrogenation of propane on silica (SBA-15) supported vanadia catalysts: A kinetic investigation [J].
Dinse, Arne ;
Khennache, Sonia ;
Frank, Benjamin ;
Hess, Christian ;
Herbert, Rita ;
Wrabetz, Sabine ;
Schloegl, Robert ;
Schomaecker, Reinhard .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 307 (1-2) :43-50
[9]   TRANSIENT HOT-STRIP METHOD FOR SIMULTANEOUSLY MEASURING THERMAL-CONDUCTIVITY AND THERMAL-DIFFUSIVITY OF SOLIDS AND FLUIDS [J].
GUSTAFSSON, SE ;
KARAWACKI, E ;
KHAN, MN .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1979, 12 (09) :1411-1421
[10]   Synthesis and hydrophobic adsorption properties of microporous/mesoporous hybrid materials [J].
Hu, Qin ;
Li, Jinjun ;
Qiao, Shizhang ;
Hao, Zhengping ;
Tian, Hua ;
Ma, Chunyan ;
He, Chi .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 164 (2-3) :1205-1212