Relative strengths of the O-H•••Cl and O-H•••F hydrogen bonds

被引：66

作者：

Caminati, W ^{[1
]}

Melandri, S ^{[1
]}

Maris, A ^{[1
]}

Ottaviani, P ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 15期

关键词：

hydrogen bonding; molecular complexes; molecular dynamics; rotational spectroscopy; supersonic jets;

D O I：

10.1002/anie.200504486

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Which bond goes where? The observed conformer of H 2O⋯ClFCH2 displays one O-H⋯Cl and two weak C-H⋯O hydrogen-bonding interactions. The dissociation energy of this conformer is estimated to be 8.5 kJ mol-1 from the centrifugal distortion effects. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：2438 / 2442

页数：5

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