Thermophysical properties and application of LiNO3-H2O working fluid

被引:25
作者
Luo, Chunhuan [1 ]
Su, Qingquan [1 ]
Mi, Wanliang [1 ]
机构
[1] Univ Sci & Technol Beijing, Sch Mech Engn, Beijing 100083, Peoples R China
来源
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID | 2013年 / 36卷 / 06期
关键词
Absorption heat pump; Lithium bromide; Lithium nitrate; COP; LITHIUM BROMIDE; THERMODYNAMIC PROPERTIES; AQUEOUS-SOLUTIONS; NITRATE; WATER; SYSTEM;
D O I
10.1016/j.ijrefrig.2013.04.018
中图分类号
O414.1 [热力学];
学科分类号
摘要
Vapor pressure (293.15 K-423.15 K, 50%-70%), specific heat capacity (303.15 K-373.15 K, 45% -60%) and specific enthalpy (303.15 K 373.15 K, 45%-60%) of LiNO3-H2O working fluid were measured. Dissolution heat of LiNO3 at 294.15 K was also determined. The corrosion behaviors of carbon steel, stainless steel 304 in LiBr and LiNO3 solutions were investigated at the temperature of 453.15 K, and the corrosivity of LiNO3 solution was obviously less severe than that of LiBr solution. Based on the measured data, performances of an absorption heat pump cycle based on LiNO3-H2O has been investigated and compared with the LiBr-H2O heat pump cycle under the same conditions. The results show that the cycle based on LiNO3-H2O has an advantage of 6.3 degrees C in the temperature grade of driving heat source against that based on LiBr H2O, while the COP based on LiNO3 H2O is slightly higher than that based on LiBr H2O. (C) 2013 Elsevier Ltd and IIR. All rights reserved.
引用
收藏
页码:1689 / 1700
页数:12
相关论文
共 21 条
[1]   A model for analysis and design of H2O-LiBr absorption heat pumps [J].
Bakhtiari, Bahador ;
Fradette, Louis ;
Legros, Robert ;
Paris, Jean .
ENERGY CONVERSION AND MANAGEMENT, 2011, 52 (02) :1439-1448
[2]   VAPOR PRESSURES OF AQUEOUS SOLUTIONS OF SILVER NITRATE, OF AMMONIUM NITRATE, AND OF LITHIUM NITRATE [J].
CAMPBELL, AN ;
FISHMAN, JB ;
RUTHERFORD, G ;
SCHAEFER, TP ;
ROSS, L .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1956, 34 (02) :151-159
[3]  
Chen D., 2009, HEAT PUMP WATER HEAT
[4]   Thermodynamic evaluation of new absorbent mixtures of lithium bromide and organic salts for absorption refrigeration machines [J].
Donate, M ;
Rodriguez, L ;
De Lucas, A ;
Rodríguez, JF .
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID, 2006, 29 (01) :30-35
[5]  
Gao L.L., 2008, CHEM EXPT TECHNIQUES
[6]   PROPERTIES OF LIOH AND LINO3 AQUEOUS-SOLUTIONS [J].
GIERSZEWSKI, PJ ;
FINN, PA ;
KIRK, DW .
FUSION ENGINEERING AND DESIGN, 1990, 13 (01) :59-71
[7]   Certain physical properties of the alkali nitrates and chlorides. [J].
Haigh, FL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1912, 34 :1137-1159
[8]  
Jia S.Y., 2005, BASIC CHEM EXPT
[9]   Experimental research on characteristics of corrosion-resisting nickel alloy tube used in triple-effect LiBr/H2O absorption chiller [J].
Jiangzhou, S ;
Wang, RZ .
APPLIED THERMAL ENGINEERING, 2001, 21 (11) :1161-1173
[10]   Thermodynamic properties of lithium bromide-water solutions at high temperatures [J].
Kaita, Y .
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID, 2001, 24 (05) :374-390