Coherence in charge and energy transfer in molecular junctions

被引:26
|
作者
White, Alexander J. [1 ]
Peskin, Uri [2 ,3 ]
Galperin, Michael [1 ]
机构
[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
[2] Technion Israel Inst Technol, Schulich Fac Chem, IL-32000 Haifa, Israel
[3] Technion Israel Inst Technol, Lise Meitner Ctr Computat Quantum Chem, IL-32000 Haifa, Israel
来源
PHYSICAL REVIEW B | 2013年 / 88卷 / 20期
关键词
QUANTUM-INTERFERENCE; PHYSIOLOGICAL TEMPERATURE; CONDUCTION JUNCTIONS; SINGLE-MOLECULE; TRANSPORT; ELECTRONICS; COMPLEXES; CURRENTS; SYSTEMS; LIGHT;
D O I
10.1103/PhysRevB.88.205424
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We consider the effects of dephasing on field-induced coherent charge and energy transport in molecular junctions. Within generic models we show that dephasing controls the relative intensities of energy and charge fluxes, and that the dependence of the energy flux on the dephasing rate is nonmonotonic. We further demonstrate the possibility for laser-controlled charge-energy separation in multiterminal molecular junctions, a prerequisite for engineering low-heating stable nanoscale devices.
引用
收藏
页数:9
相关论文
共 50 条
  • [1] KINETICS OF CHARGE TRANSFER PROCESSES IN MOLECULAR JUNCTIONS
    Petrov, E. G.
    UKRAINIAN JOURNAL OF PHYSICS, 2011, 56 (07): : 721 - 731
  • [2] Charge Transfer through Redox Molecular Junctions in Nonequilibrated Solvents
    Kirchberg, Henning
    Thorwart, Michael
    Nitzan, Abraham
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2020, 11 (05): : 1729 - 1737
  • [3] Energy transfer, coherence, and decoherence in molecular aggregates
    Silbey, Robert J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [4] Molecular Junctions: Introduction and Physical Foundations, Nanoelectrical Conductivity and Electronic Structure and Charge Transfer in Organic Molecular Junctions
    Saade Abdalkareem Jasim
    Mustafa M. Kadhim
    Venu KN
    Indah Raya
    Sarah Jawad Shoja
    Wanich Suksatan
    Muneam Hussein Ali
    ehsan kianfar
    Brazilian Journal of Physics, 2022, 52
  • [5] Molecular Junctions: Introduction and Physical Foundations, Nanoelectrical Conductivity and Electronic Structure and Charge Transfer in Organic Molecular Junctions
    Jasim, Saade Abdalkareem
    Kadhim, Mustafa M.
    Kn, Venu
    Raya, Indah
    Shoja, Sarah Jawad
    Suksatan, Wanich
    Ali, Muneam Hussein
    Kianfar, Ehsan
    BRAZILIAN JOURNAL OF PHYSICS, 2022, 52 (02)
  • [6] Raman scattering from molecular conduction junctions: Charge transfer mechanism
    Oren, Michal
    Galperin, Michael
    Nitzan, Abraham
    PHYSICAL REVIEW B, 2012, 85 (11)
  • [7] Photoinduced charge and energy transfer in molecular wires
    Gilbert, Melina
    Albinsson, Bo
    CHEMICAL SOCIETY REVIEWS, 2015, 44 (04) : 845 - 862
  • [8] Time scale issues for charge transfer and energy storage using semiconductor junctions
    Univ of Rochester, Rochester, United States
    Sol Energ Mater Sol Cells, 1-4 (331-333):
  • [9] Entanglement, energy transfer and coherence visibility in small molecular systems
    Meng, Xiangjia
    Zheng, Yujun
    JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2014, 47 (06)
  • [10] Resolving charge transfer mechanisms in molecular tunnel junctions using dynamic charge transfer and static current-voltage measurements
    Cao, Liang
    Zhang, Ziyu
    Thompson, Damien
    Qi, Dong-Chen
    Nijhui, Christian A.
    JOURNAL OF MATERIALS CHEMISTRY C, 2024, 12 (05) : 1701 - 1709