Combined Experimental and Computational Study on Catalytic Cyclocoupling of Epoxides and CO2 Using Porphyrin-Based Cu(II) Metal-Organic Frameworks with 2D Coordination Networks

被引：5

作者：

Murayama, Tsukasa ^{[1
]}

Asano, Masayuki ^{[1
]}

Ohmura, Tetsushi ^{[2
]}

Usuki, Arimitsu ^{[2
]}

Yasui, Takeshi ^{[1
]}

Yamamoto, Yoshihiko ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Pharmaceut Sci, Dept Basic Med Sci, Chikusa Ku, Nagoya, Aichi 4648601, Japan

[2] Toyota Cent Res & Dev Labs Inc, Nagakute, Aichi 4801192, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2018年 / 91卷 / 03期

关键词：

CARBON-DIOXIDE; CYCLIC CARBONATES; ENERGY-STORAGE; CAPTURE; CYCLOADDITION; PURIFICATION; CHALLENGES; OXIRANES;

D O I：

10.1246/bcsj.20170371

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cyclocoupling of epoxides and CO2 was investigated using porphyrin-based Cu(II) metal-organic frameworks with 2D coordination networks. A variety of mono- and disubstituted epoxides were transformed into cyclic carbonates under mild and neat conditions. Several control experiments were carried out to elucidate that the catalytically active site is the dicopper paddle wheel unit rather than the copper porphyrin complex moiety. The proposed mechanism was corroborated by density functional theory calculations of a model paddle wheel unit.

引用

页码：383 / 390

页数：8

共 67 条

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