Ethylene Oligomerization beyond Schulz-Flory Distributions

被引：87

作者：

Britovsek, George J. P. ^{[1
]}

Malinowski, Robert ^{[1
]}

McGuinness, David S. ^{[2
]}

Nobbs, James D. ^{[1
]}

Tomov, Atanas K. ^{[1
]}

Wadsley, Andrew W. ^{[3
]}

Young, Craig T. ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Univ Tasmania, Sch Phys Sci Chem, Hobart, Tas 7001, Australia

[3] Stochast Simulat Ltd, Perth, WA 6017, Australia

来源：

ACS CATALYSIS | 2015年 / 5卷 / 11期

基金：

英国工程与自然科学研究理事会; 澳大利亚研究理事会;

关键词：

oligomerization; catalysis; distributions; alpha-olefins; ethylene; trimerization; tetramerization; recurrence; ZIEGLER-NATTA CATALYSTS; ALPHA-OLEFINS; MECHANISTIC INVESTIGATIONS; POLYMERIZATION; TETRAMERIZATION; DIMERIZATION; TI(OR')(4)/ALR3; METALLACYCLE; COMPLEXES; STATE;

D O I：

10.1021/acscatal.5b02203

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oligomerization of ethylene produces alpha-olefin distributions ranging from Schulz-Flory distributions to alternating and selective oligomer distributions that can be mathematically analyzed and characterized by recurrence relations.

引用

页码：6922 / 6925

页数：4

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