Enhanced Visible-light-driven Photocatalytic Performance of In2O3-loaded TiO2 Nanocubes with Exposed (001) Facet

被引:7
作者
Gao Bifen [1 ]
Wan Jianfeng [1 ]
Hu Desheng [1 ]
Chen Yilin [1 ]
Lin Bizhou [1 ]
机构
[1] Huaqiao Univ, Coll Mat Sci & Engn, Dept Appl Chem, Xiamen 361021, Peoples R China
基金
中国国家自然科学基金;
关键词
Photocatalytic activity; Heterojunction; Crystal facet; In2O3-loaded TiO2 nanocube; SINGLE-CRYSTALS; EFFICIENT; HETEROJUNCTION; MICROSPHERES; DEGRADATION; FABRICATION; PERCENTAGE; NANOSHEETS;
D O I
10.1007/s40242-017-7133-7
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The heterostructures of In2O3 nanoparticle loaded on anatase TiO2 nanocube with exposed (001) facet (In2O3/TiO2-nanocube) were fabricated via a two-step hydrothermal process. The crystal phase, morphology, micro-structure and photo-absorption property of the products were characterized by FESEM, TEM, XRD, and UV-Vis diffuse reflectance spectroscopy. The results showed that the percentage of exposed (001) facet of TiO2 nanocube was about 33%. In2O3 nanoparticles were successfully decorated on the surface of TiO2 nanocube to form the In2O3/TiO2 heterojunction. Photocurrent measurements confirmed that (001) faceted surface was advantageous for the charge carrier migration and separation in the composites. In comparison with bare TiO2 nanocube and In2O3/TiO2-nanoparticle, the In2O3/TiO2-nanocube heterostructures exhibited enhanced activity toward the degradation of rhodamine B and tetracycline under visible light irradiation, which was attributed to the synergic effect of In2O3/TiO2 heterojunction and the exposure of (001) facet.
引用
收藏
页码:934 / 938
页数:5
相关论文
共 24 条
[1]   Indium oxide nanocluster doped TiO2 catalyst for activation of molecular O2 [J].
Amoli, Vipin ;
Farooqui, Saleem ;
Rai, Aditya ;
Santra, Chiranjit ;
Rahman, Sumbul ;
Sinha, Anil Kumar ;
Chowdhury, Biswajit .
RSC ADVANCES, 2015, 5 (82) :67089-67092
[2]   Faceted Titania Nanocrystals Doped with Indium Oxide Nanoclusters As a Superior Candidate for Sacrificial Hydrogen Evolution without Any Noble-Metal Cocatalyst under Solar Irradiation [J].
Amoli, Vipin ;
Sibi, Malayil Gopalan ;
Banerjee, Biplab ;
Anand, Mohit ;
Maurya, Abhayankar ;
Farooqui, Saleem Akhtar ;
Bhaumik, Asim ;
Sinha, Anil Kumar .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (01) :810-822
[3]   Visible light activated photocatalytic degradation of tetracycline by a magnetically separable composite photocatalyst: Graphene oxide/magnetite/cerium-doped titania [J].
Cao, Muhan ;
Wang, Peifang ;
Ao, Yanhui ;
Wang, Chao ;
Hou, Jun ;
Qian, Jin .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 467 :129-139
[4]   Constructing Hierarchical Spheres from Large Ultrathin Anatase TiO2 Nanosheets with Nearly 100% Exposed (001) Facets for Fast Reversible Lithium Storage [J].
Chen, Jun Song ;
Tan, Yi Ling ;
Li, Chang Ming ;
Cheah, Yan Ling ;
Luan, Deyan ;
Madhavi, Srinivasan ;
Boey, Freddy Yin Chiang ;
Archer, Lynden A. ;
Lou, Xiong Wen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (17) :6124-6130
[5]   Corundum-Type In2O3 Urchin-Like Nanostructures: Synthesis Derived from Orthorhombic InOOH and Application in Photocatalysis [J].
Chen, Li-Yong ;
Liang, Yi ;
Zhang, Zu-De .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (07) :903-909
[6]   Efficient decomposition of organic compounds with FeTiO3/TiO2 heterojunction under visible light irradiation [J].
Gao, Bifen ;
Kim, Yong Joo ;
Chakraborty, Ashok Kumar ;
Lee, Wan In .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 83 (3-4) :202-207
[7]   Enhanced visible-light-driven photocatalytic H2-production activity of CdS-loaded TiO2 microspheres with exposed (001) facets [J].
Gao, Bifen ;
Yuan, Xia ;
Lu, Penghui ;
Lin, Bizhou ;
Chen, Yilin .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2015, 87 :171-176
[8]   Synthesis of Titania Nanosheets with a High Percentage of Exposed (001) Facets and Related Photocatalytic Properties [J].
Han, Xiguang ;
Kuang, Qin ;
Jin, Mingshang ;
Xie, Zhaoxiong ;
Zheng, Lansun .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (09) :3152-+
[9]  
Lalitha K, 2014, INDIAN J CHEM A, V53, P472
[10]   Controlled Synthesis of Anatase TiO2 Single Crystals with Dominant {001} Facets from TiO2 Powders [J].
Li, Hongmei ;
Zeng, Yangsu ;
Huang, Tongcheng ;
Piao, Lingyu ;
Liu, Min .
CHEMPLUSCHEM, 2012, 77 (11) :1017-1021