Contrasting crystallographic signatures of Ag(I)- and Cu(II)-N6,N6′-bisadenine complexes:: extended vs. foldback geometries

被引：30
|
作者：
Mishra, Ashutosh Kumar [1 ]
Purohit, Chandra Shekhar [1 ]
Verma, Sandeep [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
来源：
CRYSTENGCOMM | 2008年 / 10卷 / 10期
关键词：
D O I：
10.1039/b811205n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report crystallographic studies with N6,N6'-crosslinked bisadenine derivative, where complexation with Ag(I) exhibits a pentacoordination mode affording a molecular box, while interaction with Cu(II) results in an intramolecular complex.
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收藏
页码：1296 / 1298
页数：3
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